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Dichloridobis(2-methoxy-dibenzo[c,e][1,2]oxaphospho-rine-κP)platinum(II) trichloro-methane solvate.
| Content Provider | Europe PMC |
|---|---|
| Author | Holczbauer, Tamás Keglevich, György Kerényi, Andrea Czugler, Mátyás |
| Copyright Year | 2009 |
| Abstract | The title compound, [PtCl2(C13H11O2P)2]·CHCl3, has a rare PtCl2 bridging of two dibenzooxaphosphorine ligands through the metal atom. The PtII ion is in a slightly distorted square-planar environment. The trichloromethane solvent molecule shows rotational disorder (major occupancy is 0.75) and is placed near to the inversion centre at (1/2, 1/2, 0) in channels parallel to the a axis. The solvent molecule is linked to the complex molecule via intermolecular bifurcated C—H⋯Cl and C—H⋯O hydrogen bonds. The crystal structure is further stabilized by π–π interactions involving the benzene rings, with a centroid–centroid distance of 3.658 (8) Å. |
| Journal | Acta crystallographica. Section E, Structure Reports Online |
| Volume Number | 65 |
| PubMed Central reference number | PMC2968428 |
| Issue Number | Pt 3 |
| Issue Number | pt 3 |
| PubMed reference number | 21582112 |
| e-ISSN | 16005368 |
| DOI | 10.1107/s1600536809006643 |
| Language | English |
| Publisher | International Union of Crystallography |
| Publisher Date | 2009-02-28 |
| Access Restriction | Open |
| Rights License | This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. © Holczbauer et al. 2009 |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Condensed Matter Physics Materials Science |
