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Enantioselektive katalytische Hydrierung von α‐(Acetylamino)‐zimtsäure mit einem Rhodium‐Phosphankomplex in wäßriger Lösung
| Content Provider | Semantic Scholar |
|---|---|
| Author | Nagel, Ulrich Kinzel, Elke |
| Copyright Year | 1986 |
| Abstract | Enantioselective Catalytic Hydrogenation of α-(Acetylamino)cinnamic Acid with a Rhodium Phosphane Complex in Aqueous Solution The synthesis of [(3R,4R)-3,4-bis(diphenylphosphino)-1,1-dimethylpyrrolidinium-P,P'](1,5cyclooctadiene)rhodium bis(tetrafluoroborate) (5) is described. With this water-soluble catalyst the sodium salt 6c of a-(Acetylamino)cinnamic acid (6a) is hydrogenated in aqueous solution to give (S)-N-acetylphenylalanine with 90% ee. |
| Starting Page | 1731 |
| Ending Page | 1733 |
| Page Count | 3 |
| File Format | PDF HTM / HTML |
| DOI | 10.1002/cber.19861190525 |
| Volume Number | 119 |
| Alternate Webpage(s) | http://anorganik.uni-tuebingen.de/aknagel/VEROEFFEN/ENANTIO4.PDF |
| Alternate Webpage(s) | https://doi.org/10.1002/cber.19861190525 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |