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A binuclear iminodiacetato-copper(II) complex with the N,N'-bis(pyridine-4-ylmethylene)hydrazine ligand as spacer
| Content Provider | Semantic Scholar |
|---|---|
| Author | Kundu, Nabanita Chatterjee, Pabitra Baran Chaudhury, Muktimony Tiekink, Edward R. T. |
| Copyright Year | 2005 |
| Abstract | The centrosymmetric title compound, μ-N,N′-bis(pyridin-4-ylmethylene)hydrazine-bis[diaqua(iminodiacetato)copper(II)], [Cu2(C4H5NO4)2(C12H10N4)(H2O)4], features a trans-N2O4 donor set that defines a heavily distorted octahedral geometry. Coordination is provided by a tridentate iminodiacetate (ida) dianion, one end of a bidentate bridging N,N′-bis(pyridin-4-ylmethylene)hydrazine ligand, which is disposed about a centre of inversion, and two water molecules. Extensive hydrogen bonding leads to a cohesive crystal structure. |
| File Format | PDF HTM / HTML |
| DOI | 10.1107/S1600536805021549 |
| Volume Number | 61 |
| Alternate Webpage(s) | https://journals.iucr.org/e/issues/2005/08/00/ng6155/ng6155.pdf |
| Alternate Webpage(s) | https://research-repository.griffith.edu.au/bitstream/handle/10072/4915/31630_1.pdf?isAllowed=y&sequence=1 |
| Alternate Webpage(s) | https://doi.org/10.1107/S1600536805021549 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |