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Copper(II) complexes of N(4)-substituted thiosemicarbazones derived from pyridine-2-carbaldehyde: Crystal structure of a binuclear complex
| Content Provider | CUSAT-Thesis |
|---|---|
| Author | Rapheal, P. F. Manoj, E. Prathapachandra Kurup, M. R. |
| Abstract | Ten copper(II) complexes {[CuL1Cl] (1), [CuL1NO3]2 (2), [CuL1N3]2 · 2/3H2O (3), [CuL1]2(ClO4)2 · 2H2O (4), [CuL2Cl]2 (5), [CuL2N3] (6), [Cu(HL2)SO4]2 · 4H2O (7), [Cu(HL2)2] (ClO4)2 · 1/2EtOH (8), [CuL3Cl]2 (9), [CuL3NCS] · 1/2H2O (10)} of three NNS donor thiosemicarbazone ligands {pyridine-2-carbaldehyde-N(4)-p-methoxyphenyl thiosemicarbazone [HL1], pyridine-2-carbaldehyde-N(4)-2-phenethyl thiosemicarbazone [HL2] and pyridine-2-carbaldehyde N(4)-(methyl), N(4)-(phenyl) thiosemicarbazone [HL3]} were synthesized and physico-chemically characterized. The crystal structure of compound 9 has been determined by X-ray diffraction studies and is found that the dimer consists of two square pyramidal Cu(II) centers linked by two chlorine atoms. |
| Starting Page | 818 |
| Ending Page | 828 |
| Page Count | 11 |
| File Format | |
| ISSN | 02775387 |
| Journal | Polyhedron |
| Volume Number | 26 |
| Language | English |
| Publisher | ELSEVIER |
| Access Restriction | Open |
| Subject Keyword | Crystal structure Thiosemicarbazone Pyridine-2-carbaldehyde Cu(II) complex |
| Content Type | Text |
| Resource Type | Article |
| Subject | Physical and Theoretical Chemistry Inorganic Chemistry Materials Chemistry |
