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A Novel 2d Zinc(II) Coordination Polymer Based on 2,2'-bipyridine-4,4'-dicarboxylic Acid: Synthesis, Crystal Structure and Photoluminescence Property
| Content Provider | Semantic Scholar |
|---|---|
| Author | Vitiu, Aliona Croitor, Lilia Siminel, Anatolii V. Coropceanu, Eduard B. Bourosh, Paulina N. |
| Copyright Year | 2018 |
| Abstract | Two-dimensional Zn(II) coordination polymer {[Zn(bpdc)(H2O)]·dmf·H2O}n (1), where H2bpdc= 2,2′-bipyridine-4,4′-dicarboxylic acid and dmf= N,N-dimethylformamide, was obtained by hydrothermal synthesis and characterized by IR spectrum and single-crystal X-ray diffraction. The Zn(II) ion is coordinated in a distorted square pyramidal N2O3 environment by two N-atoms from one bpdc 2ligand, two carboxylate oxygen atoms from another two bpdc 2ligands and one water molecule. The crystal lattice of 1 hosts the dmf and water solvent molecules via O-H···O hydrogen bonds with crystal components. The new material reveals blue-orange luminescence upon excitation with ultraviolet light. |
| Starting Page | 30 |
| Ending Page | 35 |
| Page Count | 6 |
| File Format | PDF HTM / HTML |
| DOI | 10.19261/cjm.2017.479 |
| Volume Number | 13 |
| Alternate Webpage(s) | http://www.cjm.asm.md/sites/default/files/Abstract_ChemJMold_10.19261cjm.2018.479-Croitor.pdf |
| Alternate Webpage(s) | https://doi.org/10.19261/cjm.2017.479 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |