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A novel cadmium(II) coordination polymer with biphenyl-3,3',4,4'-tetracarboxylic acid and 4,4'-bipyridine.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Hao, Xiang-Rong Su, Zhongmin Zhao, Ya-Hui Shao, Kui-Zhan Wang, Yong |
| Copyright Year | 2005 |
| Abstract | A novel cadmium(II) coordination polymer, poly[[[bis(4,4'-bipyridine)cadmium(II)]-mu(3)-4,4'-dicarboxybiphenyl-3,3'-dicarboxylato] 0.35-hydrate], {[Cd(C(16)H(8)O(8))(C(10)H(8)N(2))(2)].0.35H(2)O}(n), was obtained by reaction of Cd(CH(3)COO)(2).3H(2)O, 4,4'-bipyridine (4,4'-bpy) and biphenyl-3,3',4,4'-tetracarboxylic acid (H(4)L) under hydrothermal conditions. Each Cd(II) atom lies at the centre of a distorted octahedron, coordinated by four O atoms from three H(2)L(2-) ligands and N atoms from two monodentate 4,4'-bpy ligands. Each H(2)L(2-) ligand coordinates to three Cd(II) atoms through two carboxylate groups, one acting as a bridging bidentate ligand and the other in a chelating bidentate fashion. Two Cd atoms, two H(2)L(2-) anions and four 4,4'-bpy ligands form a ring dimer node, which links into an extended broad zonal one-dimensional chain along the c axis. |
| File Format | PDF HTM / HTML |
| DOI | 10.1107/S0108270105028751 |
| Alternate Webpage(s) | http://journals.iucr.org/c/issues/2005/11/00/hj1069/hj1069.pdf |
| PubMed reference number | 16272583 |
| Alternate Webpage(s) | https://doi.org/10.1107/S0108270105028751 |
| Journal | Medline |
| Volume Number | 61 |
| Part | 11 |
| Journal | Acta crystallographica. Section C, Crystal structure communications |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
