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Near-infrared-sensitive materials based on photoresponsive ruthenium(II) polypyridyl complexes-functionalized lanthanide-doped upconverting nanoparticles
| Content Provider | Semantic Scholar |
|---|---|
| Author | Chen, Zhijun |
| Copyright Year | 2017 |
| Abstract | ........................................................................................................................................ 1 Chapter 1: Introduction and motivation ........................................................................................ 5 1.1 Ruthenium(II) polypyridyl complexes .................................................................................. 5 1.2 Photochemical property of Ru complexes ............................................................................. 5 1.3 Photosensitive Ru complexes ................................................................................................ 7 1.4 Bio-medical applications of photoresponsive Ru complexes ................................................ 8 1.4.1 Photorelease of neurochemical molecules ...................................................................... 8 1.4.2 Light-activated enzyme inhibition .................................................................................. 9 1.4.3 Regulating gene expression .......................................................................................... 10 1.4.4 Anti-cancer reagent ....................................................................................................... 11 1.5 Strategies for red-shifting responsive wavelength of Ru complexes................................... 13 1.6 Lanthanide-doped upconverting nanoparticles (UCNPs) .................................................... 14 1.7 Mechanism of UCNPs ......................................................................................................... 15 1.7.1 Mechanism of excited-state absorption (ESA) ............................................................. 15 1.7.2 Mechanism of energy transfer upconversion (ETU) .................................................... 16 1.7.3 Mechanism of cooperative sensitization upconversion (CSU) ..................................... 17 1.7.4 Mechanism of cross-relaxation (CR) ............................................................................ 17 1.7.5 Mechanism of photon avalanche (PA) .......................................................................... 18 1.8 Development of NIR-sensitive molecules assisted by UCNPs ........................................... 18 1.8.1 UCNP-assisted photolytic compounds ......................................................................... 19 1.8.2 UCNP-assisted photoswicthing compounds ................................................................. 20 1.8.3. UCNP-assisted photoinitiators ..................................................................................... 22 1.9 Bio-medical applications based on UCNP-assisted photosensitive compounds ................. 24 1.9.1 NIR-controlled drug delivery ........................................................................................ 24 |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | https://pure.mpg.de/rest/items/item_2428966_2/component/file_2585757/content |
| Alternate Webpage(s) | https://publications.ub.uni-mainz.de/theses/volltexte/2017/100001257/pdf/100001257.pdf |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |