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Iron-catalyzed intermolecular hydroamination of styrenes.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Huehls, Christopher Bryan Lin, Aijun Yang, Jiong |
| Copyright Year | 2014 |
| Abstract | An iron-catalyzed formal hydroamination of alkenes has been developed. It features O-benzoyl-N,N-dialkylhydroxylamines as the electrophilic nitrogen source and cyclopentylmagnesium bromide as the reducing agent for intermolecular hydroamination of styrene and derivatives with good yield and excellent Markovnikov regioselectivity. The reaction presumably proceeds through the iron-catalyzed hydrometalation of styrene followed by electrophilic amination with the electrophilic O-benzoylhydroxylamine. |
| File Format | PDF HTM / HTML |
| DOI | 10.1021/ol5013907 |
| PubMed reference number | 24983840 |
| Journal | Medline |
| Volume Number | 16 |
| Issue Number | 14 |
| Alternate Webpage(s) | https://www.thieme.de/statics/dokumente/thieme/final/en/dokumente/tw_chemistry/CFZ-Synform-Iron-Catalyzed-Intermolecular-Hydroamination-of-Styrenes.pdf |
| Alternate Webpage(s) | https://doi.org/10.1021/ol5013907 |
| Journal | Organic letters |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
