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Temperature- and salt-responsive polyoxometalate-poly(N-isopropylacrylamide) hybrid macromolecules in aqueous solution.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Zhou, Jing Yin, Panchao Chen, Xinyue Hu, Lang Liu, Tianbo |
| Copyright Year | 2015 |
| Abstract | Polyoxometalate (POM) polar head groups were covalently functionalized with poly(N-isopropylacrylamide) (PNIPAM) tails. The macromolecular hybrid demonstrates solution behavior of hydrophilic macroions by self-assembling into blackberry structures at room temperature. The hybrid behaves like an amphiphilic surfactant by forming a vesicular structure when the temperature is above the phase transition of PNIPAM. The reversible self-assembly is also salt-sensitive and the salt-induced smaller vesicular formation results from counterion-association. |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/c5cc06722g |
| PubMed reference number | 26383608 |
| Journal | Medline |
| Volume Number | 51 |
| Issue Number | 88 |
| Alternate Webpage(s) | https://pubs.rsc.org/en/content/getauthorversionpdf/C5CC06722G |
| Alternate Webpage(s) | https://doi.org/10.1039/c5cc06722g |
| Journal | Chemical communications |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |