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| Content Provider | World Health Organization (WHO)-Global Index Medicus |
|---|---|
| Author | Liu, Tianbo Yin, Panchao Zhou, Jing Hu, Lang Chen, Xinyue |
| Description | Author Affiliation: Zhou J ( University of Akron, Department of Polymer Science, Goodyear Polymer Center, Akron, OH 44325-3909, USA. tliu@uakron.edu.); |
| Abstract | Polyoxometalate (POM) polar head groups were covalently functionalized with poly(N-isopropylacrylamide) (PNIPAM) tails. The macromolecular hybrid demonstrates solution behavior of hydrophilic macroions by self-assembling into blackberry structures at room temperature. The hybrid behaves like an amphiphilic surfactant by forming a vesicular structure when the temperature is above the phase transition of PNIPAM. The reversible self-assembly is also salt-sensitive and the salt-induced smaller vesicular formation results from counterion-association. |
| ISSN | 13597345 |
| Volume Number | 51 |
| Journal | Chemical Communications |
| Issue Number | 88 |
| e-ISSN | 1364548X |
| Language | English |
| Publisher | Royal Society of Chemistry |
| Publisher Date | 2015-10-01 |
| Publisher Place | Great Britain (UK) |
| Access Restriction | Subscribed |
| Subject Keyword | Acrylic Resins Chemistry Macromolecular Substances Organosilicon Compounds Surface-Active Agents Temperature Cesium Chlorides Chemical Synthesis Oxides Phase Transition Tungsten Compounds Water Journal Article |
| Content Type | Text |
| Resource Type | Article |
| Subject | Ceramics and Composites Chemistry Surfaces, Coatings and Films Materials Chemistry Metals and Alloys Electronic, Optical and Magnetic Materials Catalysis |
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