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catena-Poly[[(1,10-phenanthroline-5,6-dione-κ2 N,N′)lead(II)]-μ-terephthalato-κ2 O 1:O 4]
| Content Provider | Semantic Scholar |
|---|---|
| Author | Cong, Fang-Di Yu, Feng-Yang Wei, Zhen Hai Ng, Seik Weng |
| Copyright Year | 2009 |
| Abstract | The Pb(II) atom in the polymeric title compound, [Pb(C(8)H(4)O(4))(C(12)H(6)N(2)O(2))](n), is chelated by the N-heterocycle, and adjacent atoms are bridged by rigid terephthalate dianions into a linear chain. The Pb(II) atom is stereochemically active in a ψ-square-pyramidal coordination geometry in which the lone-pair electrons occupy a basal site. When three other weaker Pb⋯O inter-actions are considered, the geometry is a ψ-dodeca-hedron. |
| Starting Page | m1544 |
| Ending Page | m1544 |
| Page Count | 1 |
| File Format | PDF HTM / HTML |
| DOI | 10.1107/S1600536809046455 |
| PubMed reference number | 21578584 |
| Journal | Medline |
| Volume Number | 65 |
| Alternate Webpage(s) | https://doi.org/10.1107/S1600536809046455 |
| Journal | Acta crystallographica. Section E, Structure reports online |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |