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Cobalt(I)-Catalyzed 1,4-Hydrovinylation Reactions of 1,3-Dienes with Functionalized Terminal Alkenes under Mild Conditions.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Hilt, Gerhard Lueers, Steffen |
| Copyright Year | 2002 |
| Abstract | Synthesis 2002, No. 5, 08 04 2002. Article Identifier: 1437-210X,E;2002,0,05,0609,0618,ftx,en;Z03202SS.pdf. © Georg Thieme Verlag Stuttgart · New York ISSN 0039-7881 Abstract : The cobalt-catalyzed 1,4-hydrovinylation of acyclic 1,3-dienes with various functionalized terminal alkenes is described. The mild reaction conditions are significant because they considerably reduce the amount of side products and for non acceptor-substituted alkenes the branched products are formed exclusively. The CoBr2(dppe) catalyst system controls the regiochemistry of the hydrovinylation process. Unsymmetrical 1,3-dienes yield products, where the new carbon-carbon bond is formed at the less substituted end of the 1,3-diene. |
| Starting Page | 609 |
| Ending Page | 618 |
| Page Count | 10 |
| File Format | PDF HTM / HTML |
| DOI | 10.1002/chin.200230071 |
| Volume Number | 33 |
| Alternate Webpage(s) | http://www.xiuzhengrd.com/ejournals/pdf/synthesis/doi/10.1055/s-2002-23549.pdf |
| Alternate Webpage(s) | https://doi.org/10.1002/chin.200230071 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
