NDLI: Iridium-catalyzed enantioselective direct vinylogous allylic alkylation of coumarins† †Dedicated to Professor E. J. Corey on the occasion of his 90th birthday. ‡ ‡Electronic supplementary information (ESI) available: Experimental details, characterization and analytical data. See DOI: 10.1039/c8sc02

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Iridium-catalyzed enantioselective direct vinylogous allylic alkylation of coumarins† †Dedicated to Professor E. J. Corey on the occasion of his 90th birthday. ‡ ‡Electronic supplementary information (ESI) available: Experimental details, characterization and analytical data. See DOI: 10.1039/c8sc02

Content Provider	Semantic Scholar
Author	Sarkar, Rahul Mitra, Sankash Mukherjee, Santanu
Copyright Year	2018
Abstract	The first iridium-catalyzed enantioselective vinylogous allylic alkylation of coumarins is presented. Using easily accessible linear allylic carbonates as the allylic electrophile, this reaction installs unfunctionalized allyl groups at the γ-position of 4-methylcoumarins in an exclusively branched-selective manner generally in high yields with an excellent level of enantioselectivity (up to 99 : 1 er).
Starting Page	5767
Ending Page	5772
Page Count	6
File Format	PDF HTM / HTML
DOI	10.1039/c8sc02041h
Alternate Webpage(s)	http://www.rsc.org/suppdata/c8/sc/c8sc02041h/c8sc02041h1.pdf
Alternate Webpage(s)	https://pubs.rsc.org/en/content/articlepdf/2018/sc/c8sc02041h
Alternate Webpage(s)	http://www.rsc.org/suppdata/c8/sc/c8sc02041h/c8sc02041h2.pdf
Alternate Webpage(s)	https://ftp.ncbi.nlm.nih.gov/pub/pmc/oa_pdf/e5/0c/SC-009-C8SC02041H.PMC6050583.pdf
PubMed reference number	30079186
Alternate Webpage(s)	https://doi.org/10.1039/c8sc02041h
Volume Number	9
Journal	Chemical science
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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