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Scandium-catalysed intermolecular hydroaminoalkylation of olefins with aliphatic tertiary amines† †Electronic supplementary information (ESI) available: Full experimental details for catalytic procedures and characterization data. See DOI: 10.1039/c6sc02129h Click here for additional data file.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Nako, Adi E. Oyamada, Juzo Nishiura, Masayoshi Hou, Zhaomin |
| Copyright Year | 2016 |
| Abstract | A homoleptic scandium trialkyl complex in combination with a borate compound served as an excellent catalyst for the C-H addition of aliphatic tertiary amines to olefins. This highly regiospecific, 100% atom efficient C-H bond alkylation reaction was applicable to a wide variety of tertiary amines and olefins, including functionalised styrenes and unactivated α-olefins. This work represents the first example of rare-earth catalysed olefin hydroaminoalkylation and also the first example of catalytic C-H addition of aliphatic tertiary amines to olefins with any catalyst. |
| Starting Page | 6429 |
| Ending Page | 6434 |
| Page Count | 6 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/c6sc02129h |
| PubMed reference number | 28451099 |
| Journal | Medline |
| Volume Number | 7 |
| Alternate Webpage(s) | http://pubs.rsc.org/en/content/articlepdf/2016/sc/c6sc02129h |
| Alternate Webpage(s) | https://doi.org/10.1039/c6sc02129h |
| Journal | Chemical science |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
