NDLI: Accelerated Ru–Cu Trinuclear Cooperative C−H Bond Functionalization of Carbazoles: A Kinetic and Computational Investigation

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Accelerated Ru–Cu Trinuclear Cooperative C−H Bond Functionalization of Carbazoles: A Kinetic and Computational Investigation

Content Provider	Scilit
Author	Jones, Alexander W. Rank, Christian K. Becker, Yanik Malchau, Christian Funes-Ardoiz, Ignacio Maseras, Feliu Patureau, Frederic William
Copyright Year	2018
Description	Journal: Chemistry – A European Journal The mechanism of a trinuclear cooperative dehydrogenative C-N bond forming reaction is investigated in this work, which avoids the use of chelate assisting directing groups. Two new highly efficient Ru/Cu co-catalyzed systems were identified, allowing three orders of magnitude greater TOFs than the previous state of the art. In-depth kinetic studies were performed in combination with advanced DFT calculations, which reveal a decisive rate-determining trinuclear Ru-Cu cooperative reductive elimination step (CRE).
Related Links	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6221041/pdf
Ending Page	15184
Page Count	7
Starting Page	15178
e-ISSN	15213765
DOI	10.1002/chem.201802886
Journal	Chemistry – A European Journal
Issue Number	57
Volume Number	24
Language	English
Publisher	Wiley-Blackwell
Publisher Date	2018-10-12
Access Restriction	Open
Subject Keyword	Journal: Chemistry – A European Journal Organic Chemistry C-h Bond Activation * Cross Dehydrogenative Coupling * Dehydrogenative Amination * Cooperative Reductive Elimination * Trinuclear Catalysis
Content Type	Text
Resource Type	Article

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