NDLI: Allylic C–H Alkynylation via Copper-Photocatalyzed Cross-Dehydrogenative Coupling

Content Provider	Scilit
Author	Almasalma, Ahmad A. Mejía, Esteban
Copyright Year	2019
Description	An efficient, novel photocatalyzed allylic-alkynylation methodology via copper-based cross-dehydrogenative coupling (CDC) is described. Different types of 1,4-enyne compounds were synthesized in one step at room temperature using copper(I) terpyridyl complex as photocatalyst/initiator. This procedure is an improvement and to some extent complementary to previously reported thermal CDC methods. Preliminary investigations on the reaction mechanism are also presented.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0039-1690014.pdf
Ending Page	536
Page Count	8
Starting Page	529
ISSN	00397881
e-ISSN	1437210X
DOI	10.1055/s-0039-1690014
Journal	Synthesis
Issue Number	04
Volume Number	52
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2019-07-25
Access Restriction	Open
Subject Keyword	Journal: Synthesis Organic Chemistry C–h Functionalization Allylic-alkynylation
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Catalysis

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Allylic C–H Alkynylation via Copper-Photocatalyzed Cross-Dehydrogenative Coupling