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Excitation line dependence of the symmetric chain-stretching mode of linear-chain, mixed-valence palladium complexes
| Content Provider | Scilit |
|---|---|
| Author | Clark, R. J. H. Croud, V. B. |
| Copyright Year | 1986 |
| Description | Journal: Journal of Physics C: Solid State Physics The wavenumber, nu$ _{1}$, of the symmetric chain-stretching mode of linear-chain, halogen-bridged mixed-valence palladium complexes of the type $(Pd(LL)_{2})(Pd(LL)_{2}X_{2})(ClO_{4})_{4}$, where LL=1,2-diaminoethane (en), 1,2-diaminopropane (pn) or 1,3-diaminopropane (tn) for X=Cl, and LL=en for X=Br, increases as the wavenumber of the excitation line ( nu$ _{0}$) increases. For all four complexes studied nu$ _{1}$ consists of several components whose relative intensities change with a change in nu$ _{0}$. Possible explanations for the dependence of the components of nu$ _{1}$ on nu$ _{0}$ are considered. |
| Related Links | http://iopscience.iop.org/article/10.1088/0022-3719/19/18/018/pdf |
| Ending Page | 3474 |
| Page Count | 8 |
| Starting Page | 3467 |
| ISSN | 00223719 |
| DOI | 10.1088/0022-3719/19/18/018 |
| Journal | Journal of Physics C: Solid State Physics |
| Issue Number | 18 |
| Volume Number | 19 |
| Language | English |
| Publisher | IOP Publishing |
| Publisher Date | 1986-06-30 |
| Access Restriction | Open |
| Subject Keyword | Journal: Journal of Physics C: Solid State Physics Chain Stretching Mode Symmetric Chain Stretching |
| Content Type | Text |
| Resource Type | Article |
| Subject | Physics and Astronomy Condensed Matter Physics Engineering |
