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Synthesis, Structure And Protective Properties Of Tetra Sodium Nitrilo- Tris- Methylene Phosphonate Zincate Tridecahydrate Na4 [ N( Ch2 Po3)
| Content Provider | Scilit |
|---|---|
| Author | Kodolov, Vladimir I. Zaikov, Gennady Efremovich Haghi, A. K. |
| Copyright Year | 2016 |
| Description | ................................................................................................. 290 19.1 Introduction .................................................................................. 290 19.2 Experiment ................................................................................... 291 19.3 Results and Discussion ................................................................ 291 19.4 Conclusions .................................................................................. 297 Keywords .............................................................................................. 297 References ............................................................................................. 297 ABSTRACT The authors have synthesized a coordination compound, which has the properties of corrosion inhibitor and studied its structure by the X-ray scattering method, X-ray photoelectron spectroscopy and Raman spectroscopy. The compound obtained has a chelate structure, which is stable during storing and provides high degree of steel protection against corrosion in neutral aqueous media. The crystal lattice belongs to triclinic system, the spatial group is 1P , Z=2, a = 11.2208(2) Å, B = 11.2666(3) Å, c = 12.3286(3) Å, α = 108.455(2)°, b = 97.168(2)°, g = 117.103(2)°. The complex is chelate; the internal coordination sphere includes three five-membered cycles N-C-P-O-Zn with the common bond Zn-N. Zinc is coordinated in the distorted trigonal-bipyramidal configuration, which includes an oxygen atom of the neighboring molecule of the complex. Book Name: Nanostructures, Nanomaterials, and Nanotechnologies to Nanoindustry |
| Related Links | https://content.taylorfrancis.com/books/download?dac=C2013-0-25105-3&isbn=9780429156557&doi=10.1201/b16956-33&format=pdf |
| Ending Page | 332 |
| Page Count | 10 |
| Starting Page | 323 |
| DOI | 10.1201/b16956-33 |
| Language | English |
| Publisher | Informa UK Limited |
| Publisher Date | 2016-04-19 |
| Access Restriction | Open |
| Subject Keyword | Book Name: Nanostructures, Nanomaterials, and Nanotechnologies To Nanoindustry Inorganic Chemistry Crystallography Raman Spectroscopy Corrosion Structure Sodium Coordination Chelate Compound Complex |
| Content Type | Text |
| Resource Type | Chapter |
