NDLI: Direct Isocyanomethylation of Nitroarenes via the Vicarious Nucleophilic Substitution of Hydrogen with Phenylthiomethyl Isocyanide Carbanion

Content Provider	Scilit
Author	Makosza, Mieczysław Kinowski, Andrzej Ostrowski, Stanisław
Copyright Year	1993
Description	Reaction of nitroarenes with phenylthiomethyl isocyanide in the presence of potassium tert-butoxide results in the introduction of the isocyanomethyl substituent into positions ortho or para to the nitro group. The products of the reaction when subjected to mild hydrolysis can be converted into nitrobenzylic amines or their formyl derivatives.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-1993-35863.pdf
Ending Page	1217
Page Count	3
Starting Page	1215
ISSN	00397881
e-ISSN	1437210X
DOI	10.1055/s-1993-35863
Journal	Synthesis
Issue Number	12
Volume Number	1993
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	1993-01-01
Access Restriction	Open
Subject Keyword	Journal: Synthesis Organic Chemistry
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Catalysis

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Direct Isocyanomethylation of Nitroarenes via the Vicarious Nucleophilic Substitution of Hydrogen with Phenylthiomethyl Isocyanide Carbanion