NDLI: How Does Nucleophilic Aromatic Substitution in Nitroarenes Really Proceed: General Mechanism

Content Provider	Scilit
Author	Mąkosza, Mieczysław
Copyright Year	2017
Description	Dedicated to Professor Herbert Mayr on the occasion of his $70^{th}$ birthday On the basis of previously published experimental studies and ab initio calculations, a general corrected mechanism of nucleophilic aromatic substitution was formulated. It was shown that conventional nucleophilic substitution of halogens is a slow secondary reaction whereas nucleophilic substitution of hydrogen is the fast primary process. The general mechanism embraces both of these alternative and complementary reactions.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0036-1588444.pdf
Ending Page	3254
Page Count	8
Starting Page	3247
ISSN	00397881
e-ISSN	1437210X
DOI	10.1055/s-0036-1588444
Journal	Synthesis
Issue Number	15
Volume Number	49
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2017-06-06
Access Restriction	Open
Subject Keyword	Journal: Synthesis Organic Chemistry Vicarious Substitution Nucleophilic Addition
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Catalysis

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How Does Nucleophilic Aromatic Substitution in Nitroarenes Really Proceed: General Mechanism