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Synthesis of Substituted Fluorenes by Cascade Allenylation, Electrocyclization and Intramolecular Friedel-Crafts Reaction of 1,3-Diene-Substituted Propargylic Alcohols
| Content Provider | Scilit |
|---|---|
| Author | Xu, Xiangsheng Li, Xiaoqing Li, Tao Shao, Jiangbin |
| Copyright Year | 2013 |
| Description | A concise, one-step synthesis of substituted fluorenes through $TiCl_{4}$-promoted cascade allenylation, electrocyclization and intramolecular Friedel–Crafts reaction of 1,3-diene-substituted propargylic alcohols has been developed. An interesting substituent-dependent regioselectivity was observed. |
| Related Links | http://pdfs.semanticscholar.org/1df5/c597c88a701f85d82aee3b17284aa9ac5a2c.pdf |
| Ending Page | 388 |
| Page Count | 6 |
| Starting Page | 383 |
| ISSN | 09365214 |
| e-ISSN | 14372096 |
| DOI | 10.1055/s-0032-1318104 |
| Journal | Synlett |
| Issue Number | 03 |
| Volume Number | 24 |
| Language | English |
| Publisher | Georg Thieme Verlag KG |
| Publisher Date | 2013-01-21 |
| Access Restriction | Open |
| Subject Keyword | Organic Chemistry Electrocyclization Intramolecular reactions |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry |