NDLI: Ruthenium-Catalyzed Enantioselective Propargylation of Indoles with Propargylic Alcohols

Content Provider	Scilit
Author	Nishibayashi, Yoshiaki Kanao, Keiichiro Matsuzawa, Hiroshi Miyake, Yoshihiro
Copyright Year	2008
Description	Ruthenium-catalyzed enantioselective propargylation of 1-(triisopropylsilyl)-1H-indoles with propargylic alcohols gives the corresponding β-propargylated indoles in good yields with high enantioselectivity. Reactions with 1-(1-naphthyl)prop-2-yn-1-ol achieve the highest enantioselectivity (up to 95% ee).
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0028-1083217.pdf
Ending Page	3873
Page Count	5
Starting Page	3869
ISSN	00397881
e-ISSN	1437210X
DOI	10.1055/s-0028-1083217
Journal	Synthesis
Issue Number	23
Volume Number	2008
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2008-11-06
Access Restriction	Open
Subject Keyword	Journal: Synthesis Organic Chemistry Friedel-crafts Alkylation Propargylic Alcohols
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Catalysis

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Ruthenium-Catalyzed Enantioselective Propargylation of Indoles with Propargylic Alcohols