NDLI: Pyridine Chromium Tricarbonyl Complexes: Completely Stereoselective Aldol-Type Reactions Between 2-Ethylpyridine Chromium Tricarbonyl and Non-Enolisable Aldehydes

Content Provider	Scilit
Author	Davies, Stephen G. Shipton, Mark R.
Copyright Year	1991
Description	α-Deprotonation of 2-ethylpyridine chromium tricarbonyl with lithium diisopropylamide followed by addition of non-enolisable aldehydes, benzaldehyde and 2,2-dimethylpropanal, leads to single diastereoisomers of the corresponding aldol-type products, which on oxidative decomplexation give erythro-1-phenyl-2-(2-pyridyl)-1-propanol and erythro-2,2-dimethyl-4-(2-pyridyl)-3-pentanol, respectively, in good yield.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-1991-20614.pdf
Ending Page	26
Page Count	2
Starting Page	25
ISSN	09365214
e-ISSN	14372096
DOI	10.1055/s-1991-20614
Journal	Synlett
Issue Number	01
Volume Number	1991
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	1991-01-01
Access Restriction	Open
Subject Keyword	Journal: Synlett Organic Chemistry
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry

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Pyridine Chromium Tricarbonyl Complexes: Completely Stereoselective Aldol-Type Reactions Between 2-Ethylpyridine Chromium Tricarbonyl and Non-Enolisable Aldehydes