NDLI: Stereoselective Sulfonate Aldol Reactions: Asymmetric Synthesis of α,β-Substituted β-Hydroxy Sulfonates

Content Provider	Scilit
Author	Harnying, Wacharee Kitisriworaphan, Wipaporn Pohmakotr, Manat Enders, Dieter
Copyright Year	2007
Description	An efficient asymmetric synthesis of β-hydroxy sulfonates is described via stereocontrolled aldol reactions of sulfonates using 1,2:5,6-di-O-isopropylidene-α-d-allofuranose as the chiral auxiliary. The aldol reactions with aromatic aldehydes yielded predominantly syn adducts in very good yields and excellent diastereo- and enantiomeric excesses (de, ee ≥98%).
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-2007-986642.pdf
Ending Page	2532
Page Count	4
Starting Page	2529
ISSN	09365214
e-ISSN	14372096
DOI	10.1055/s-2007-986642
Journal	Synlett
Issue Number	16
Volume Number	2007
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2007-09-12
Access Restriction	Open
Subject Keyword	Journal: Synlett Organic Chemistry Aldol Reaction Sugar Auxiliary Hydroxy Sulfonates
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry

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Stereoselective Sulfonate Aldol Reactions: Asymmetric Synthesis of α,β-Substituted β-Hydroxy Sulfonates