NDLI: Palladium-Catalyzed Silylation of Aryl Chlorides with Hexamethyldisilane

Content Provider	Scilit
Author	McNeill, E.
Editor	Barder, T. E. Buchwald, S. L.
Copyright Year	2007
Description	Aryl silanes are highly useful intermediates in the synthesis of functionalized arenes due to the ability of the silyl group to direct the attack of an electrophile to the ipso position. Herein, an excellently general and convenient method for the preparation of aryl silanes from the corresponding chlorides is reported. The synthetic utility of the new silylation reaction was demonstrated by the one-pot conversion of several aryl chlorides into the corresponding aryl iodides.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-2007-991326.pdf
Ending Page	1296
Page Count	1
Starting Page	1296
ISSN	18611958
e-ISSN	1861194X
DOI	10.1055/s-2007-991326
Journal	Synfacts
Issue Number	12
Volume Number	2007
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2007-11-22
Access Restriction	Open
Subject Keyword	Journal: Synfacts Organic Chemistry
Content Type	Text
Resource Type	Article

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Palladium-Catalyzed Silylation of Aryl Chlorides with Hexamethyldisilane