NDLI: Palladium-Catalyzed Silylation of Aryl Chlorides with Bulky Dialkoxydisilanes

Content Provider	Scilit
Author	Shimokawa, Jun Yorimitsu, Hideki Fukui, Keitaro Saito, Hayate
Copyright Year	2020
Description	Arylsilanes bearing a bulky alkoxy group on the silicon were synthesized from aryl chlorides and dialkoxydisilanes under reaction conditions utilizing SingaCycle-A3 as a palladium precatalyst and lithium benzoate in wet DMA. This report proposes the first direct and catalytic method for introducing tert-butoxy- or 1-adamantyloxysilyl groups onto various aryl moieties through the silylation reaction.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0039-1690877.pdf
Ending Page	1332
Page Count	5
Starting Page	1328
ISSN	09365214
e-ISSN	14372096
DOI	10.1055/s-0039-1690877
Journal	Synlett
Issue Number	13
Volume Number	31
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2020-04-02
Access Restriction	Open
Subject Keyword	Organic Chemistry
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry

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