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A Novel Catalytic Three-Component Synthesis (Kabachnick-Fields Reaction) of α-Aminophosphonates from Ketones
| Content Provider | Scilit |
|---|---|
| Author | Matveeva, Elena D. Zefirov, Nikolay S. Podrugina, Tatyana A. Tishkovskaya, Elena V. Tomilova, Larisa G. |
| Copyright Year | 2003 |
| Description | A novel and highly convenient catalytic variant of the synthesis of α-aminophosphonates on basis of the Kabachnik-Fields reaction [three-component reaction of ketones, diethylphosphite and either benzylamine (series a) of ammonium carbonate (series b)] in the presence of tetra-tert-butylphthalocyanines has been developed. This method affords α-aminophosphonates in acceptable yields for various ketones, including cyclic, sterically hindered and cage ketones. The unsubstituted α-aminophosphonic acids were also obtained from the corresponding esters of series b. |
| Related Links | http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-2003-42118.pdf |
| Ending Page | 2324 |
| Page Count | 4 |
| Starting Page | 2321 |
| ISSN | 09365214 |
| e-ISSN | 14372096 |
| DOI | 10.1055/s-2003-42118 |
| Journal | Synlett |
| Issue Number | 15 |
| Volume Number | 2003 |
| Language | English |
| Publisher | Georg Thieme Verlag KG |
| Publisher Date | 2003-11-07 |
| Access Restriction | Open |
| Subject Keyword | Organic Chemistry Α-aminophosphonates Tetra-tert-butylphthalocyanines Α-aminophosphonic Acids |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry |
