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Selective C–Si Bond Formation through C–H Functionalization

Content Provider	Scilit
Author	Sharma, Upendra Sharma, Ritika Kumar, Rakesh Kumar, Inder Singh, Bikram
Copyright Year	2015
Description	Silylation of hydrocarbons is one of the most important transformations due to the diverse application of organosilanes. Continuous progress is being made in organosilane synthesis particularly through direct C–H activation/functionalization. This minireview compiles various processes reported for C–Si bond formation from 2000–2014, through C–H activation/functionalization (proximal and remote) and metal-free approaches. 1 Introduction 2 C–Si Bond Formation through C–H Activation in Intermolecular Fashion 2.1 C–Si Bond Formation through Direct $C(sp^{2}$)–H Activation 2.2 C–Si Bond Formation through Directing Group Assisted $C(sp^{2}$)–H Activation 2.3 C–Si Bond Formation through $sp^{3}$ C–H Activation 3 C–Si Bond Formation through Proximal C–H Activation/Functionalization in Intramolecular Fashion 3.1 Intramolecular C–Si Bond Formation through $C(sp^{2}$)–H Activation 3.2 Intramolecular C–Si Bond Formation through $C(sp^{3}$)–H Activation 4 Siloles Synthesis through Heteroannulation 5 C–Si Bond Formation through Remote C–H Activation 6 C–Si Bond Formation through C–O Bond Cleavage 7 Metal-Free Methods for C–Si Bond Formation 8 Summary and Outlook
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0034-1380435.pdf
Ending Page	2366
Page Count	20
Starting Page	2347
ISSN	00397881
e-ISSN	1437210X
DOI	10.1055/s-0034-1380435
Journal	Synthesis
Issue Number	16
Volume Number	47
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2015-07-09
Access Restriction	Open
Subject Keyword	Journal: Synthesis Inorganic Chemistry
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Catalysis

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