NDLI: Ascorbic Acid Promoted Metal-Free Synthesis of Aryl Sulfides with Anilines Nitrosated in Situ by tert-Butyl Nitrite

Content Provider	Scilit
Author	Cai, Chun Bu, Mei-Jie Lu, Guo-Ping
Copyright Year	2015
Description	A mild, metal-free synthesis of aryl sulfides has been disclosed. Aryl diazonium ion was generated by the in situ nitrosation of aniline, and it was reduced by ascorbic acid (vitamin C) to form aryl radical, which underwent a thiolation with disulfide to yield aryl sulfide. The reaction proceeded smoothly without heating or irradiation. This strategy was also expanded to the synthesis of aryl selenides.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0034-1378738.pdf
Ending Page	1846
Page Count	6
Starting Page	1841
ISSN	09365214
e-ISSN	14372096
DOI	10.1055/s-0034-1378738
Journal	Synlett
Issue Number	13
Volume Number	26
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2015-07-16
Access Restriction	Open
Subject Keyword	Organic Chemistry Carbon–sulfur Bond Formation
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry

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Ascorbic Acid Promoted Metal-Free Synthesis of Aryl Sulfides with Anilines Nitrosated in Situ by tert-Butyl Nitrite