NDLI: Metal-Free Oxidative C=C Bond Cleavage of Electron-Deficient Enamines Promoted by tert-Butyl Hydroperoxide

Content Provider	Scilit
Author	Adib, Mehdi Pashazadeh, Rahim Gohari, Seyed Jamal Adin Shahsavari, Fatemeh
Copyright Year	2017
Description	A novel tert-butyl hydroperoxide (TBHP)-promoted oxidative C=C double-bond cleavage of enamines is described. Heating a solution of an electron-deficient enamine in chlorobenzene at 80 °C in the presence of TBHP for two hours led to cleavage of the C=C bond. This study offers a new strategy to carry out C=O double-bond formation by the use of TBHP.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0036-1588990.pdf
Ending Page	1485
Page Count	5
Starting Page	1481
ISSN	09365214
e-ISSN	14372096
DOI	10.1055/s-0036-1588990
Journal	Synlett
Issue Number	12
Volume Number	28
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2017-04-19
Access Restriction	Open
Subject Keyword	Organic Chemistry Atomic, Molecular and Chemical Physics Tert-butyl Hydroperoxide
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry

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Metal-Free Oxidative C=C Bond Cleavage of Electron-Deficient Enamines Promoted by tert-Butyl Hydroperoxide