NDLI: Iron-Catalyzed Oxidative C–C and C–O Coupling of Halophenols to α-Substituted β-Keto Esters

Content Provider	Scilit
Author	Pappo, Doron Regev, Almog Shalit, Hadas
Copyright Year	2015
Description	The iron-catalyzed oxidative cross-coupling of halophenols to α-substituted β-keto esters takes place through one of two modes: oxidative C–C coupling or oxidative C–O coupling. A mechanistic investigation revealed that the chemoselectivity of these reactions is determined by the electronic and steric properties of the two coupling partners.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0034-1380360.pdf
Ending Page	1725
Page Count	10
Starting Page	1716
ISSN	00397881
e-ISSN	1437210X
DOI	10.1055/s-0034-1380360
Journal	Synthesis
Issue Number	12
Volume Number	47
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2015-03-26
Access Restriction	Open
Subject Keyword	Journal: Synthesis Organic Chemistry
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Catalysis

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Iron-Catalyzed Oxidative C–C and C–O Coupling of Halophenols to α-Substituted β-Keto Esters