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Regioselective Palladium(II)-Catalyzed Desulfitative Heck-Type Reaction: Access to α-Benzyl-β-keto Esters from Baylis-Hillman Adducts and Sodium Sulfinates
| Content Provider | Scilit |
|---|---|
| Author | Nagaiah, Kommu Raju, Kammari Bal Mari, Vellakkaran |
| Copyright Year | 2013 |
| Description | A new palladium(II)-catalyzed desulfitative Heck-Type arylation from sodium arenesulfinates and Baylis–Hillman adducts for the synthesis of highly functionalized α-benzyl-β-keto ester derivatives in good to excellent yields has been developed. This methodology is simple and mild, it can utilize halogen bearing building blocks, and it has excellent regioselectivity. |
| Related Links | http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0033-1339663.pdf |
| Ending Page | 2874 |
| Page Count | 8 |
| Starting Page | 2867 |
| ISSN | 00397881 |
| e-ISSN | 1437210X |
| DOI | 10.1055/s-0033-1339663 |
| Journal | Synthesis |
| Issue Number | 20 |
| Volume Number | 45 |
| Language | English |
| Publisher | Georg Thieme Verlag KG |
| Publisher Date | 2013-08-15 |
| Access Restriction | Open |
| Subject Keyword | Journal: Synthesis Organic Chemistry Baylis–hillman Adducts Α-benzyl-β-keto Esters |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry Catalysis |