NDLI: Polysilanes on surfaces

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Polysilanes on surfaces

Content Provider	Royal Society of Chemistry (RSC)
Author	Fujiki, Michiya Naito, Masanobu
Copyright Year	2008
Abstract	For chain-like polymers on surfaces, the relationship between chain topology and inherent physical properties has long been puzzling due to the lack of proper models and detection systems with ultrahigh sensitivity and high accuracy. Among various chain-like polymers, soluble organopolysilane is one suitable model for elucidating the uniqueness of chain-like polymers on surfaces because of its (1) controllable molecular length, polydispersity, stiffness, and terminal group by an adequate molecular design, a careful synthesis, and a precise purification, and (2) highly luminescent chromophore due to Siσ–Siσ* transition of the Si main chain. This review comprehensively covers the works on (i) molecular imaging with scanning probe microscopy, (ii) tethering on surfaces by a grafting-to approach, (iii) self-assembly, (iv) structural phase transition, (v) orientational phase transition, and (vi) chiroptical switching, memory and amplification in single and double layer films deposited on solid surfaces. This knowledge and understanding may stimulate advanced studies on polymer-based nanoscience, nanotechnology, and nanofabrication as well as in traditional surface chemistry and polymer physics.
Starting Page	211
Ending Page	223
Page Count	13
File Format	HTM / HTML PDF
ISSN	1744683X
Volume Number	4
Issue Number	2
Journal	Soft Matter
DOI	10.1039/b710423e
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Dispersity Self-assembly Network topology Scanning probe microscopy Memory Surface science Stiffness Nanolithography Nanotechnology Physics Chromophore Phase transition
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics

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