NDLI: Influence of La2O3 composition in MgO–La2O3 mixed oxide-supported Co catalysts on the hydrogen yield in glycerol steam reforming

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Sustainable Energy & Fuels Vol - 1 Issue - 1

Influence of La₂O₃ composition in MgO–La₂O₃ mixed oxide-supported Co catalysts on the hydrogen yield in glycerol steam reforming

Content Provider	Royal Society of Chemistry (RSC)
Author	Surendar, M. Rao, K. S. Rama Prasad, P. S. Sai Padmakar, D. Lingaiah, N.
Copyright Year	2017
Abstract	MgO–La2O3 mixed oxide (MLx) supports with varying La2O3 content (x = 1, 2, 3, 4, and 5 by wt) were synthesized by a co-precipitation method. A constant composition (20 wt%) of an active metal, cobalt, was loaded on MLx supports by the wet impregnation method. The physico-chemical properties of these solids were determined by BET surface area, ICP-OES, XRD, H2-TPR, CO2-TPD, FT-IR, H2-pulse chemisorption and CHN techniques. All the catalysts were evaluated for hydrogen production by vapor phase glycerol steam reforming at atmospheric pressure. Partial substitution of La in LaCoO3 with MgO has increased the reducibility of the perovskite, enhanced the dispersion of the active metal and played a vital role in carbon removal from the active site. The best catalytic activity with 100% glycerol conversion to gas products (H2, CO, CH4 and CO2) and a maximum hydrogen yield of 72.8% has been achieved for 20 wt% of the Co/1MgO : 3La2O3 catalyst at 700 °C. The catalyst activity also remained stable up to 35 h on stream analysis.
Starting Page	354
Ending Page	361
Page Count	8
File Format	HTM / HTML PDF
ISSN	23984902
Volume Number	1
Issue Number	2
Journal	Sustainable Energy & Fuels
DOI	10.1039/c6se00023a
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Chemisorption Atmospheric pressure Hydrogen Active site Glycerol Inductively coupled plasma atomic emission spectroscopy Fourier-transform infrared spectroscopy Cobalt Carbon BET X-ray crystallography Perovskite China MLx Steam reforming Coprecipitation
Content Type	Text
Resource Type	Article
Subject	Fuel Technology Renewable Energy, Sustainability and the Environment Energy Engineering and Power Technology

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