NDLI: Honeycomb-like Co–B amorphous alloy catalysts assembled by a solution plasma process show enhanced catalytic hydrolysis activity for hydrogen generation

Please wait, while we are loading the content...

Elucidating active species and mechanism of the direct oxidation of benzene to phenol with hydrogen peroxide catalyzed by vanadium-based catalysts using DFT calculations

Fabrication of microparticles with controllable internal woodpile structures for highly efficient sensing applications

A facile electrochemical route for fast deposition of featherlike tellurium microstructures

A close-up on doxorubicin binding to γ-cyclodextrin: an elucidating spectroscopic, photophysical and conformational study

A thermodynamic analysis of methanation reactions of carbon oxides for the production of synthetic natural gas

Honeycomb-like Co–B amorphous alloy catalysts assembled by a solution plasma process show enhanced catalytic hydrolysis activity for hydrogen generation

Zone-selective photoelectronic measurements of the local bonding and electronic dynamics associated with the monolayer skin and point defects of graphite

Changes in morphological and nano-mechanical properties of the milk fat globule membrane during processing

Phase-separated binary polymers spin coated onto microwrinkles

Synthesis and visible light photoactivity of anatase Ag and garlic loaded TiO₂ nanocrystalline catalyst

The development of affinity capture devices—a nanoscale purification platform for biological in situ transmission electron microscopy

InCl₃ catalyzed domino route to 2H-chromene-2-ones via [4 + 2] annulation of 2-hydroxyarylaldehydes with α-oxoketene dithioacetal under solvent-free conditions

Revisiting differences in the thermoresponsive behavior of PNIPAAm and PMEO2MA aqueous solutions

Multi-carbazole derivatives: new dyes for highly efficient dye-sensitized solar cells

Fabrication of magnetic drug-loaded polymeric composite nanofibres and their drug release characteristics

Silver nanoparticles in a polyether-block-polyamide copolymer towards antimicrobial and antifouling membranes

Bulky mesoporous TiO₂ structure

Synthesis of the novel trimeric benzamides—potential inhibitors of protein–protein interactions

Mechanical properties of carbon nanotube–PMMA based hybrid coatings: the importance of surface chemistry

Improvement in CO sensing characteristics by decorating ZnO nanorod arrays with Pd nanoparticles and the related mechanisms

Cellulose solubilities in carboxylate-based ionic liquids

β-Lactam-host defence peptide conjugates as antibiotic prodrug candidates targeting resistant bacteria

Synthesis, characterization and cytotoxicity study of magnetic (Fe₃O₄) nanoparticles and their drug conjugate

Nanogravimetric study of lead underpotential deposition on selenium thin films as a semiconductor alloy formation procedure

CO₂ capture from flue gas at high temperatures by new ionic liquids with high capacity

Polyethylenimine covalently grafted on mesostructured porous silica for CO₂ capture

Mononuclear and dinuclear complexes of manganese(iii) and Iron(iii) supported by 2-salicyloylhydrazono-1,3-dithiane ligand: synthesis, characterization and magnetic properties

Autothermal reforming of isobutanol

Morphology of colloidal metal pyrophosphate salts

Fabrication of MnO₂/graphene oxide composite nanosheets and their application in hydrazine detection

Proton-transfer paths in CH⋯O hydrogen bonds

Macroscopic and microscopic Li⁺ transport parameters in cubic garnet-type “Li_6.5La_2.5Ba_0.5ZrTaO₁₂” as probed by impedance spectroscopy and NMR

Label-free detection of target DNA sequence and single-base mismatch in hepatitis C virus corresponding to oligonucleotide by resonance light scattering technique

Collision-induced dissociation of singly and doubly charged Cu^II–cytidine complexes in the gas phase: an experimental and computational study

Immobilization of chiral catalysts on magnetite nanoparticles for highly enantioselective asymmetric hydrogenation of aromatic ketones

Synthesis, structural characterization, solvatochromism, and ion-binding studies of a ditopic receptor based on 2-(4-[2,2′: 6′,2′′]terpyridin-4′-yl-phenyl)-1H-phenanthro[9,10-d] imidazole (tpy-HImzphen) unit

Back cover

RSC Advances Vol - 2 Issue - 5

RSC Advances Vol - 2 Issue - 4

RSC Advances Vol -1

RSC Advances Vol -0

Honeycomb-like Co–B amorphous alloy catalysts assembled by a solution plasma process show enhanced catalytic hydrolysis activity for hydrogen generation

Content Provider	Royal Society of Chemistry (RSC)
Author	Zhang, Li Wu, Ping Chu, Wei Tong, Dong Ge
Copyright Year	2012
Abstract	A novel solution plasma process was developed to assemble honeycomb-like Co–B amorphous alloy catalysts with 253.33 m2 g−1 specific surface area using triethanolamine (TEA) as a soft template. The sample was characterized by X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy and transmission electron microscopy. During catalytic hydrolysis of hydrous hydrazine (H2NNH2) for hydrogen generation, the hydrolysis activity and hydrogen selectivity of the honeycomb-like Co–B is superior to Rh nanoparticles and Co–B nanospheres. Meanwhile, the sample also exhibits excellent catalytic performance in the catalytic hydrolysis of ammonia borane (NH3BH3) and sodium borohydride (NaBH4) for hydrogen generation, respectively. The H2 generation rate of 28.9, 105.8, and 262.8 L h−1 g−1catalyst for the hydrolysis reactions of H2NNH2, NH3BH3 and NaBH4, respectively, can be achieved. Meanwhile, the honeycomb-like Co–B is found to be a highly stable catalyst as it provides 18 360, 54 000, and 93 727 total turnovers in the hydrolytic dehydrogenations of H2NNH2, NH3BH3 and NaBH4, respectively, after being tested for 30 h. The enhanced catalytic performance for the honeycomb-like Co–B catalyst is attributed to the high specific surface area and the enhanced intrinsic activity resulting from its unique honeycomb-like structure.
Starting Page	2369
Ending Page	2376
Page Count	8
File Format	HTM / HTML PDF
ISSN	20462069
Volume Number	2
Issue Number	6
Journal	RSC Advances
DOI	10.1039/c2ra01321e
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Cell membrane Hydrogen Specific surface area Photoemission spectroscopy Amorphous metal Scanning electron microscope Intrinsic activity X-ray crystallography Hydrolysis Transmission electron microscopy Ammonia borane Triethanolamine Sodium borohydride Hydrazine X-ray photoelectron spectroscopy
Content Type	Text
Resource Type	Article
Subject	Chemistry Chemical Engineering

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Model Ag/HOPG catalysts: preparation and STM/XPS study

Retraction: Honeycomb-like Co-B amorphous alloy catalysts assembled by a solution plasma process show enhanced catalytic hydrolysis activity for hydrogen generation.

A facile method to fabricate polystyrene/silver composite particles and their catalytic properties

Study of potassium promoter effect for Ru/AC catalysts for ammonia synthesis

Enhanced visible-light-driven photocatalysis of surface nitrided electrospun TiO₂ nanofibers

In₂O₃ nanocubes/carbon nanofibers heterostructures with high visible light photocatalytic activity

Efficient visible-light-induced hydrogen evolution from water splitting using a nanocrystalline nickel phosphide catalyst

Self-assembly synthesis of reduced graphene oxide-supported platinum nanowire composites with enhanced electrocatalytic activity towards the hydrazine oxidation reaction

Catalytic and physicochemical characterizations of novel oxide-supported copper catalysts. Part 1.—Hydrosol-prepared Cu/TiO₂ and effects of prereduction on hydrogenation and oligomerization of acetone

Honeycomb-like Co–B amorphous alloy catalysts assembled by a solution plasma process show enhanced catalytic hydrolysis activity for hydrogen generation

Similar Documents

Model Ag/HOPG catalysts: preparation and STM/XPS study

Retraction: Honeycomb-like Co-B amorphous alloy catalysts assembled by a solution plasma process show enhanced catalytic hydrolysis activity for hydrogen generation.

A facile method to fabricate polystyrene/silver composite particles and their catalytic properties

Study of potassium promoter effect for Ru/AC catalysts for ammonia synthesis

Enhanced visible-light-driven photocatalysis of surface nitrided electrospun TiO2 nanofibers

In2O3 nanocubes/carbon nanofibers heterostructures with high visible light photocatalytic activity

Efficient visible-light-induced hydrogen evolution from water splitting using a nanocrystalline nickel phosphide catalyst

Self-assembly synthesis of reduced graphene oxide-supported platinum nanowire composites with enhanced electrocatalytic activity towards the hydrazine oxidation reaction

Catalytic and physicochemical characterizations of novel oxide-supported copper catalysts. Part 1.—Hydrosol-prepared Cu/TiO2 and effects of prereduction on hydrogenation and oligomerization of acetone

Honeycomb-like Co–B amorphous alloy catalysts assembled by a solution plasma process show enhanced catalytic hydrolysis activity for hydrogen generation

Enhanced visible-light-driven photocatalysis of surface nitrided electrospun TiO₂ nanofibers

In₂O₃ nanocubes/carbon nanofibers heterostructures with high visible light photocatalytic activity

Catalytic and physicochemical characterizations of novel oxide-supported copper catalysts. Part 1.—Hydrosol-prepared Cu/TiO₂ and effects of prereduction on hydrogenation and oligomerization of acetone