NDLI: Freezing and glass transition phenomena for 1,2-dichloroethane under high pressure as revealed by fluorescence spectroscopy

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RSC Advances Vol - 2 Issue - 4

RSC Advances Vol -1

RSC Advances Vol -0

Freezing and glass transition phenomena for 1,2-dichloroethane under high pressure as revealed by fluorescence spectroscopy

Content Provider	Royal Society of Chemistry (RSC)
Author	Benniston, Andrew C. Harriman, Anthony Alamiry, Mohammed A. H. Copley, Graeme
Copyright Year	2012
Abstract	The viscosity of 1,2-dichloroethane increases steadily with increasing pressure, as does the density, refractive index and polarizability of this solvent. The pressure dependence for each of these properties can be monitored by a combination of absorption and fluorescence spectroscopy carried out in the presence of a fluorescent molecular rotor that responds to changes in the local environment. At 20 °C, dichloroethane freezes under an applied pressure of ca. 370 MPa, causing sudden extinction of the fluorescence of the molecular rotor due to the opaque nature of the frozen solvent. However, this same emission is enhanced dramatically if a small amount of inert polymer is present in the solution. The behaviour is interpreted in terms of the polymeric solute promoting establishment of a glassy matrix with reasonably good optical transparency for emission spectroscopy.
Starting Page	1936
Ending Page	1941
Page Count	6
File Format	HTM / HTML PDF
ISSN	20462069
Volume Number	2
Issue Number	5
Journal	RSC Advances
DOI	10.1039/c2ra00848c
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Viscosity 1,2-Dichloroethane Spectroscopy Polarizability Fluorescence Polymer Correlation and dependence Solvent Composite material
Content Type	Text
Resource Type	Article
Subject	Chemistry Chemical Engineering

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Freezing and glass transition phenomena for 1,2-dichloroethane under high pressure as revealed by fluorescence spectroscopy

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