NDLI: Key aspects of l-threoninium picrate single crystal: an excellent organic nonlinear optical material with a high laser-induced damage threshold

Content Provider	Royal Society of Chemistry (RSC)
Author	Gupta, Shashikant Philip, J. Maurya, K. K. Vijayan, N. Thukral, Kanika Krishna, Anuj Jayaramakrishnan, V. Singh, Budhendra Das, Subhasis Bhagavannarayana, G.
Copyright Year	2014
Abstract	Recent trends focuses on the usage of nonlinear optical materials owing to their increasing demand in frontier areas of optical communication and switching applications. In the present work single crystal of L-threoninium picrate, an excellent material for nonlinear optical applications was grown using conventional slow evaporation solution technique to meet the increasing demand of photonics industry. The lattice parameters of the grown crystal were analysed by using powder X-ray diffraction, and it was found that it crystallised in monoclinic system with space group P21. The strain in the lattice of the grown crystal was calculated using Hall–Williamson relation. Crystalline perfection of the grown crystal was assessed using high resolution X-ray diffraction technique and observed that quality of crystal was fairly good. Optical transmission analysis and band gap evaluation were performed using UV-Vis spectroscopy. Laser damage threshold value for the crystal was also measured and was found to be higher than most of reported organic single crystals. Optical homogeneity of the crystal and birefringence was evaluated using modified channel spectrum method. Thermal behaviour of the grown specimen was examined by using photopyroelectric technique. Further its various mechanical properties, such as hardness, stiffness, young's modulus, were measured using nanoindentation technique.
Starting Page	56188
Ending Page	56199
Page Count	12
File Format	HTM / HTML PDF
ISSN	20462069
Volume Number	4
Issue Number	99
Journal	RSC Advances
DOI	10.1039/c4ra09410g
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Monoclinic crystal system Nanoindentation Hardness Photonics X-ray crystallography Young's modulus Williamson Ultraviolet\u2013visible spectroscopy Optical communication Picric acid Birefringence The Strain Band gap Nonlinear optics Space group Crystal structure
Content Type	Text
Resource Type	Article
Subject	Chemistry Chemical Engineering

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