NDLI: Synthesis and characterization of molecularly imprinted polymer of N-maleoylchitosan-grafted-2-acrylamido-2-methylpropanesulfonic acid and its controlled delivery and recognition of bovine serum albumin

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Polymer Chemistry Vol - 2 Issue - 8

Polymer Chemistry Vol - 2 Issue - 7

Polymer Chemistry Vol - 2 Issue - 6

Polymer Chemistry Vol - 2 Issue - 5

Polymer Chemistry Vol - 2 Issue - 4

Polymer Chemistry Vol - 2 Issue - 3

Polymer Chemistry Vol - 2 Issue - 2

Polymer Chemistry Vol -1

Synthesis and characterization of molecularly imprinted polymer of N-maleoylchitosan-grafted-2-acrylamido-2-methylpropanesulfonic acid and its controlled delivery and recognition of bovine serum albumin

Content Provider	Royal Society of Chemistry (RSC)
Author	Anirudhan, T. S. Sandeep, S.
Copyright Year	2011
Abstract	In this study a novel molecularly imprinted polymer matrix, namely protein-imprinted N-maleoylchitosan-grafted-2-acrylamido-2-methylpropanesulfonic acid polymer (MIP) matrix was prepared by using bovine serum albumin (BSA) as a template. The characteristics of the MIP were investigated using FTIR, SEM, XRD and Zeta Potential Analyses. The effects of monomer to template ratio, cross linking density, porogen, pH and ionic strength on the loading of BSA into the MIP were investigated. The adsorption studies showed that the MIP exhibits good recognition for BSA, as compared to non-imprinted polymer (NIP). The experimental adsorption isotherms of BSA onto MIP and NIP were determined and well fitted by Sips model with a maximum binding capacity of 113.51 mg g−1 for MIP and 76.39 mg g−1 for NIP. A pseudo-second-order kinetic model adequately described the kinetic rate in comparison to a pseudo-first-order model. In vitro release profiles of model drug from the MIP were investigated in physiological buffered solution using a UV/vis spectrophotometer. In addition, the drug release mechanism was analyzed by fitting the amount of drug released into Peppa's potential equation.
Starting Page	2052
Ending Page	2061
Page Count	10
File Format	HTM / HTML PDF
ISSN	17599954
Volume Number	2
Issue Number	9
Journal	Polymer Chemistry
DOI	10.1039/c1py00059d
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Zeta Potential Analyses Bovine serum albumin Polymer Buffer solution X-ray crystallography BSA Adsorption Ionic strength Molecularly imprinted polymer FB Vis Monomer Spectrophotometry
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Biochemistry Bioengineering Biomedical Engineering Polymers and Plastics

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