NDLI: ‘One pot’ synthesis of well-defined poly(aminophosphonate)s: time for the Kabachnik–Fields reaction on the stage of polymer chemistry

Content Provider	Royal Society of Chemistry (RSC)
Author	Zhang, Yaling Wei, Yen Yang, Bin Zhu, Chongyu Tao, Lei Zhao, Yuan
Copyright Year	2014
Abstract	A multicomponent reaction (MCR) has been carried out on the platform of controlled radical polymerization (CRP) to construct a ‘one pot’ MCR-CRP system for the facile preparation of well-defined functional polymers. In the current work, a novel ‘one pot’ system has been built through a combination of the Kabachnik–Fields (KF) reaction and reversible addition fragmentation chain transfer (RAFT) polymerization. Compared to a traditional stepwise method and polymer post-polymerization modification, this novel ‘one pot’ system exhibited distinct advantages to much more facilely and efficiently prepared well-defined poly(aminophosphonate)s (polyAPPs). A series of unique polyAPPs have also been successfully prepared through this KF–RAFT system, suggesting this novel method is a general and versatile approach to prepare well-defined organophosphorous polymers.
Starting Page	1857
Ending Page	1862
Page Count	6
File Format	HTM / HTML PDF
ISSN	17599954
Volume Number	5
Issue Number	6
Journal	Polymer Chemistry
DOI	10.1039/c3py01486j
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	CRP Chain transfer Living free-radical polymerization Polymer MCR Multi-component reaction
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Biochemistry Bioengineering Biomedical Engineering Polymers and Plastics

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‘One pot’ synthesis of well-defined poly(aminophosphonate)s: time for the Kabachnik–Fields reaction on the stage of polymer chemistry