NDLI: Synthesis of polymeric dyes based on UV curable multifunctional waterborne polyurethane for textile coating

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Back cover

New Journal of Chemistry Vol - 41 Issue - 1

New Journal of Chemistry Vol -39

New Journal of Chemistry Vol -29

New Journal of Chemistry Vol -0

Synthesis of polymeric dyes based on UV curable multifunctional waterborne polyurethane for textile coating

Content Provider	Royal Society of Chemistry (RSC)
Author	Xu, Yan Wang, Chaoxia Qiang, Siyu Mao, Haiyan
Copyright Year	2017
Abstract	Three novel UV curable polymeric dyes (UVPDs) based on multifunctional waterborne polyurethanes have been successfully developed to overcome the drawbacks of thermo-curing. The functionality of the UVPDs is tailored by end-capping with 2-hydroxyethyl acrylate (HEA), pentaerythritol triacrylate (PETA) and dipentaerythritol pentaacrylate (DPEPA). The chemical structure, molecular weight and carbon–carbon double bond (CC) content of the UVPDs were investigated. The thermal properties, curing behavior and color properties of the UVPDs are also discussed. It is found that the thermal stability of the UVPDs is improved upon increasing the functionality. The incorporation of chromophores into the polyurethane chain reduces the curing efficiency. The curing behavior observations demonstrate that the UVPDs can cure rapidly upon UV irradiation, especially the ones with higher functionality. A higher degree of cross-linking and better water resistance are obtained when UVPD films are cured with 5% photoinitiator. Furthermore, the UVPDs show outstanding UV light stability. The maximum absorption wavelength and curve trend of the cotton fabrics coated with the UVPDs remain unchanged while the color of the coated cotton fabrics slightly lightens when prolonging the UV curing time. The color fastness to rubbing and washing of the coated cotton fabrics with UVPD10 can be enhanced up to 4–5 grade after curing for 60 s.
Starting Page	619
Ending Page	627
Page Count	9
File Format	HTM / HTML PDF
ISSN	11440546
Volume Number	41
Issue Number	2
Journal	New Journal of Chemistry
DOI	10.1039/c6nj03159e
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Acrylate Polyurethane PETA People for the Ethical Treatment of Animals Covalent bond Pentaerythritol UV curing Cotton Wavelength Photoinitiator
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry Catalysis

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