NDLI: Diene reactions. Part 2.—Retardation by isoprene of polymerization initiated by Ni{P(OPh)<sub>3</sub>}<sub>4</sub>+ CCl<sub>4</sub>—a novel termination reaction

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Journal of the Chemical Society, Faraday Transactions 1 Vol -85

Journal of the Chemical Society, Faraday Transactions 1 Vol -79

Journal of the Chemical Society, Faraday Transactions 1 Vol -69

Electron spin resonance observations of oxygen chemisorption on zinc oxide

Mechanism of the steam reforming of methane over a coprecipitated nickel-alumina catalyst

Adsorption of carbon monoxide by zeolite Y exchanged with different cations

Magnetic studies of zeolites. Part 2.—Magnetic properties of NiA, NiX and NiY

Sintering studies on platinum black catalysts. Part 1.—Effect of pretreatment and reaction on particle size

Thermodynamic behaviour of acridine orange in solution. Model system for studying stacking and charge-effects on self-aggregation

Prolonged irradiation of dilute aqueous solutions of redox couples

Electrochemical behaviour of mixtures of VO+2 and H₂O₂ in 1 M HClO₄ on mercury and platinized platinum

Ionization of moderately strong acids in aqueous solution. Part 2.—Further E.m.f. studies of the dissociation of the bisulphate ion

Catalysis by polyelectrolytes of the Ag⁺, Hg²⁺, and Tl³⁺ induced aquations of Co(NH₃)₅Br²⁺

Heat of dilution of aqueous solutions of polyacrylates

Metal-ion catalyzed decarboxylation of oxaloacetic acid

Studies in ion solvation in non-aqueous solvents and their aqueous mixtures. Part 15.—Free energies of transfer of cadmium chloride from water to 10–40%(w/w) methanol-water mixtures at 25°C; dissociation of CdCl⁺; use of dilute cadmium amalgam electrodes. The group II cations.

Mechanism of the cathodic reduction of acetophenone in acidic aqueous-methanolic media

Charge transfer complexes of iodine with mercaptans and related sulphur compounds

Hydrogen bonding in some adducts of oxygen bases with acids. Part 7.—Thermodynamic study by infra-red spectroscopy of the association of chloroacetic acids with some oxygen bases

Interactions in lanthanide systems. Part 2.—Raman study of aqueous cerium(III) nitrate

Similar excited state pK behaviour of xanthone and the benzophenones

Studies in the system calcium sulphate/water. Part 4.—Rehydration of hexagonal CaSO₄

Deficiency in the analysis of physical adsorption data

Catalyzed thermal decomposition of organic acids. Part 2.—Catalyzed decomposition of cyclopentane- and cycloheptane-carboxylic acids by hydrogen bromide

Kinetics of the reaction of hydrogen atoms with 1,1-difluoroethylene

Oxygen negative ion reactions with carbon dioxide and carbon monoxide. Part 2

Reaction of oxygen atoms with carbonyl compounds. Part 1.—Formaldehyde

Kinetics of ozone formation in the pulse radiolysis of oxygen gas

Flash photolysis of 2-methylbut-1-ene

Oxidation of ferrous ions by perhydroxyl radicals

Radiation chemical study of the reaction of Ni⁺, Co⁺ and Cd⁺ with N₂O. Evidence for the formation of a hyperoxidised state by oxygen atom transfer

Review of book ( Journal of the Chemical Society, Faraday Transactions 1 Vol -69 )

Temperature effect on stearic acid monolayers on water

Reactions of the hydroxy peroxy radicals HOCH₂O₂ and CH₃CHOHO₂ in aqueous solution

Proton magnetic resonance investigations of the formation of alkylammonium propionate micelles in benzene and in carbon tetrachloride

Catalytic decomposition of formic acid on sodium tungsten bronzes

Bond dissociation energies from equilibrium studies. Part 4.—The equilibrium Br₂+ CH₄⇌ HBr + CH₃Br. Determination of D(CH₃—Br) and ΔH°f(CH₃Br, g)

Diene reactions. Part 1.—Ligand exchange and π-allylic complex formation associated with the system Ni{P(OPh)₃}₄+ isoprene + CCl₄

Diene reactions. Part 2.—Retardation by isoprene of polymerization initiated by Ni{P(OPh)₃}₄+ CCl₄—a novel termination reaction

Solvent effects on the free radical polymerization of styrene

Chemical reactivity and conformational properties of growing chains. Part 1.—Study on bimolecular radical termination in styrene + methyl methacrylate copolymerization

Pulse radiolytic oxidation of chloral hydrate in oxygenated and deoxygenated aqueous solutions

Oxidation of carbon monoxide by methoxy-radicals

Reaction of hydrogen atoms with nitrous oxide

Assignment of the hydroxyl bands in the infrared spectra of zeolites X and Y. Part 1.—Na—H zeolites

Assignment of the hydroxyl bands in the infrared spectra of zeolites X and Y. Part 2.—After different pretreatments

Enthalpy of mixing of n-hexane and cyclohexane

Effusion-mass spectrometric study of thermodynamic properties of vanadium and vanadium nitride

Protolysis kinetics of some amino-acids studied by the nuclear magnetic resonance spin echo technique

Electron spin resonance study of the reaction of hydrogen atoms with hydrogen sulphide

Rational definition of rate of reaction. General method of expressing rate which leads to no anomalies in systems of changing volume

Partial molar heat capacities and structural effects of tetra-n-pentylammonium bromide in aqueous urea and aqueous sodium chloride solutions

Temperature dependence of solubility of nonelectrolytes

Sorption and desorption kinetics of the cellulose and water system. Part 2.—Low concentrations on the lowest sorption limb of the hysteresis loop

Thermodynamic properties of hydrogen and deuterium dissolved in palladium at low concentrations over a wide temperature range

Activity coefficients of C₅ to C₈ hydrocarbons in squalane and dinonyl phthalate at 30°C determined by a vacuum micro-balance technique

Effect of radical scavengers and electric fields on the γ-radiolysis of gaseous hydrogen sulphide

Applicability of the drop-weight technique to the determination of the surface tensions of liquid metals

Hydrogenation of ethylene on metal electrodes. Part 1.—Reduction of ethylene with hydrogen at a platinum electrode on open circuit

Properties of monolayers at the air/water interface. Part 2.—Effect of temperature on the double layer and water dipole contributions to the surface potential of sodium octadecyl sulphate

Nucleation in salt solutions

Kinetics of the oxidation of isopropanol by aquocobalt(III) ions in aqueous perchlorate media

Molecular complexes of substituted thiophens with σ and π acceptors. Charge transfer spectra and ionization potentials of the donors

Complex-formation between carbon tetrachloride and alkyl-substituted benzenes

Adiabatic calorimetry of organic salts. Tetra-n-hexylammonium perchlorate

Acid dissociation constant of the carboxyl radical. Pulse radiolysis studies of aqueous solutions of formic acid and sodium formate

Kinetics and thermodynamics of the formation of the monoglycinate complexes of cobalt(II), nickel(II), copper(II) and zinc(II) in water, at pressures from 1 bar to 3 kbar

Electron spin resonance study of intermolecular cation exchange between sodium iodide and the ion pairs of sodium benzophenone and sodium naphthalene in tetrahydrofuran

Radiolysis of benzene + bromobenzene solutions

Electrons in liquid alcohols at low temperatures

Homogeneous catalysis by platinum(II)—tin(II) chloride complex. Part 3.—Kinetics of isotopic exchange reaction of methanol with hydrogen

Branching intermediates in the cool flames of acetaldehyde and simple ketones

Heat capacity of the H₂O/KNaX zeolite adsorption system

Mechanism of [3-¹³C]propene ammoxidation on bismuth molybdate catalyst

Isomerization and exchange reactions of dimethylbutenes over copper-exchanged 13X type zeolites

Structure of the mercury/ethylene carbonate interface. Part 1.—Variation in double layer capacity with the nature of the electrolyte

CO₂ poisoning of the γ-alumina-catalyzed reaction of COS with SO₂

Flame photometric determinations of diffusion coefficients. Part 4.—Results for lithium, potassium, rubidium and caesium

Polymerization of ethylene on chromium oxide catalysts. Part 4.—Infra-red study of the adsorption of nitric oxide and ammonia on active catalyst

Nucleation of highly supersaturated vapours. Formation of lead and lead oxide smokes

Microwave spectroscopic studies of hydrogen exchange, isomerization and hydrogenation of unsaturated hydrocarbons on the stoichiometric electron donor–acceptor complexes of phthalocyanine with alkali metals

Light scattering study of capillary waves on water covered by monomolecular films

Pulse radiolysis of 1,4-dicyanobenzene in aqueous solutions in the presence and absence of thallium(I) ions

Ketyl radicals in aqueous solution pulse radiolysis study

Autoprotolysis constants of water + dimethyl sulphoxide mixtures at 25°C and the related free energies of transfer of OH^–

Chemisorption of carbon monoxide on tungsten. Part 1.—Desorption spectra and electron stimulated desorption

Chemisorption of carbon monoxide on tungsten. Part 2.—Lateral interaction model for desorption kinetics

Thermodynamic properties of fluorine compounds. Part 11.—Low-temperature heat capacities of the three tetrafluorobenzenes

Yield of excited singlet and triplet states in the pulse radiolysis of toluene

Observations on solvated electrons in aliphatic hydrocarbons at room temperature by pulse radiolysis

Electro-catalytic reduction of acetylene on platinum

Influence of specific adsorption of reactant and product upon charge-transfer processes in polarography. The azobenzene–hydrazobenzene system

Standard potentials of silver–silver chloride electrode at different temperatures and transfer energetics of hydrochloric acid in urea + water mixtures

Semiquinone free radicals and oxygen. Pulse radiolysis study of one electron transfer equilibria

Reaction of n-propyl radicals with oxygen, hydrogen and deuterium

Hydrogen reduction of nickel ions in molecular sieve X

Thermodynamic properties of aliphatic halogen compounds. Part 1.—Vapour pressure and critical properties of 1,1,1-trichloroethane

Thermodynamic solubility: properties of gas mixtures. Part 1.—Two component gas mixtures in water at 25°C

Kinetics and mechanism of the reactions of triethylaluminium with phenylacetylene

Oxygen species adsorbed on CeO₂/SiO₂ supported catalysts

Stability constants of some complexes of t-butyl mesityl nitroxide

Thermodynamic properties of fluorine compounds. Part 12.—Low-temperature heat capacity and entropy of 1,3,5-trichloro-2,4,6-trifluorobenzene

Manganese dioxide electrode. Part 1.—Hydrogen ion response in the absence of other cations

Manganese dioxide electrode. Part 2.—Hydrogen ion response in the presence of manganese(II) ions

Heavy atom kinetic isotope effects. Part 1.—Liquid phase decarboxylation of malonic acid

Heavy atom kinetic isotope effects. Part 2.—Nitrogen isotope effects in the decomposition of aqueous aromatic diazonium salts

Free radical yields in the radiolysis of gaseos hexafluoroethane

Abstraction of chlorine atoms from alkyl chlorides by the trimethylsilyl radical

Kinetics of ozone formation in the pulse radiolysis of oxygen + ethylene mixtures

Reactions of energetic hydrogen atoms with simple hydrocarbons. Part 1.—The effect of moderators

Gas phase equilibrium between acetaldehyde and paraldehyde, thermodynamic values for the trimerisation of acetaldehyde and the polymerisability of paraldehyde

Kinetic study of the reduction of nickel oxide near its antiferromagnetic-paramagnetic transition. Influence of the magnetic structure of the reactant on the kinetics of nucleus formation on its surface

Enthalpy of ionization of water from electro-motive force measurements

Nuclear magnetic resonance studies of preferential solvation. Part 1.—Hydrogen peroxide + water

Nuclear magnetic resonance studies of preferential solvation. Part 2.—Thermodynamic treatment and application to methanol + water solvents

Ionic solvation in methanol + water mixtures. Free energies of transfer from water

Kinetics and thermodynamics of the proton-transfer reactions of 2,4-dinitrophenol with some amine bases in chlorobenzene studied by a microwave temperature-jump method

Kinetics and thermodynamics of hydrogen-bond formation and proton-transfer in the reactions of tetrabromophenolphthalein ethyl ester with amine bases in chlorobenzene, by a microwave temperature-jump method

Kinetics of the proton-transfer reactions between 2,4-dinitrophenol and tertiary amines. Possible influence of rotation in the encounter complex

Light scattering from the surface of sodium carboxymethylcellulose in water

Dissociation constant of calcium sulphate from 25 to 50°C

Studies in H₂O + D₂O media. Part 1.—Kinetics of tritium exchange between trimethyoxybenzene and aqueous perchloric acid in H₂O + D₂O mixtures: re-evaluation of the deuterium fractionation factor for the aqueous hydrogen ion

Surface studies on graphite: desorption of surface oxide

γ-Radiolysis of gaseous hydrogen sulphide in the presence of hydrogen chloride, carbon disulphide and nitrous oxide

Surface probing of synthetic faujasites by adsorption of carbon dioxide. Part 1.—Infra-red study of carbon dioxide adsorbed on Na-Ca-Y and Na-Mg-Y zeolites

Ordered layers of aliphatic alcohols and carboxylic acids at the pure liquid/graphite interface

Appearance of sulphatoferric complexes in the oxidation of ferrous sulphate solutions. A study by pulse radiolysis

Real condition of oxidized platinum electrodes. Part 2.—Resolution of reversible and irreversible processes by optical and impedance studies

Homogeneous gas phase pyrolysis of N-t-butylacetamide

Adsorption of phenols from non-polar solvents on to silica gel

Photosensitization of free-radical polymerisation by Mn₂(CO)₁₀+C₂F₄

Free radical addition to olefins. Part 10.—Addition of dibromofluoromethyl radicals to fluoroethylenes

Structure of the mercury/ethylene carbonate interface. Part 2.—Adsorption of iodide ion from solutions of constant ionic strength

General model for the adsorption of gases on solids

Chemistry of recoil tritium atoms. Part 3.—Reactions with but-2-ene in the presence of helium, oxygen or nitrogen

Chemistry of recoil tritium atoms. Part 4.—Reactions with olefins in the presence of helium

Solvolysis of t-butyl chloride in water-rich methanol + water mixtures

Thermal decomposition of lead citrate

Frequency dependence of the electrical properties of coordination complexes of transition metals

Microcalorimetric studies. Thermal decomposition and iodination of bis(benzene)chromium, bis(benzene)-chromium iodide, and some (arene)chromium tricarbonyls

Low angle light scattering technique for the study of coagulation

Sintering studies on platinum black catalysts. Part 2.—Effect of temperature of treatment and method of preparation on the sintering process

Auger electron spectroscopy studies of clean polycrystalline gold and of the adsorption of mercury on gold

Electron spin resonance study of the reaction of O(³P) atoms with chlorine and nitrosyl chloride

Enthalpies of formation of adamantanoid compounds. Part 3.—Adamantanecarboxylic acids

Heterocoagulation of graphitized carbon blacks in aqueous solutions of sodium dodecyl sulphate

Thermodynamic studies of fluoroalcohols. Part 1.—Vapour pressures and enthalpies of vaporization

Thermodynamic studies of fluoroalcohols. Part 2.—Enthalpies and heat capacities of solution of liquid fluoroalcohols in water

The electrophoretic term of the Fuoss–Onsager conductance equation

Variation of transference numbers with concentration: a test of the Fuoss–Onsager and the Pitts equations

Ion solvation and structural effects on the transport of water in aqueous organic solvents. Glycerol + water + hydrochloric acid at 25°C

Enthalpies of immersion of bare and precovered graphon in a homologous series of n-alkanes

Effect of polyelectrolytes on the kinetics of ionic reactions. Part 2.—Decomposition of p-nitrophenyl phosphate in aqueous solutions of polycations

Electrical properties of crystalline synthetic zeolites types X and Y, exchanged with monovalent cations

Reactions of chlorine oxide radicals. Part 4.—Rate constants for the reactions Cl + OClO, O + OClO, H + OClO, NO + OClO and O + ClO

Ionic entropies of transfer from water to nonaqueous solvents

Mechanism of sulphur formation in the flash photolysis of carbonyl sulphide

Studies of radical–molecule reactions using a rotating cryostat. Reactions of hydrogen atoms with organic substrates at 77 K

Pyrolysis of cyanogen halides in the shock tube. Part 1.—Cyanogen bromide in argon diluent

Dipole moment of a termolecular charge-transfer complex

Electron spin resonance studies of decomposition intermediates in strontium and barium nitrates, including pyrolytically produced no2–3

“Structure promotion” and “structure breaking”. Heat capacities of caesium bromide, tetramethylammonium bromide and tetra-n-butylammonium bromide in several solvents from 278 to 328 K

Iron compounds in flames. Relative stabilities of Fe, FeO, FeOH and Fe(OH)²

Arrhenius parameters for silene insertion reactions

Triplet state of acetone in solution. Deactivation and hydrogen abstraction

Nature of nitric oxide and nitrogen dioxide adsorbed on chromium and nickel exchanged zeolites. Electron spin resonance and infra-red study

Experimental determination of electron affinities. Part 1.—Radicals derived from pyridine, 2-methylpyridine, 3-methylpyridine and 4-methylpyridine

Studies in isodielectric solvents. Part 1.—Standard electromotive force values of the cell H₂|HCl|AgCl–Ag in methanol and methanol + acetonitrile mixtures

Thermodynamic properties and infra-red spectra of Li₂SO₄· H₂O and Li₂SO₄· D₂O

Review of book ( Journal of the Chemical Society, Faraday Transactions 1 Vol -69 )

Reaction of acetyl radicals with buta-1,3-diene

Irreversible thermodynamic parameters for isothermal transport processes in aqueous rubidium chloride

Electron spin resonance spectra of the reaction products of copper(II) hydroxide suspensions in methanol with hydrogen peroxide and of polycrystalline copper(II) hydroxide and copper(II) peroxide

Thermodynamics of anhydrous potassium ferrocyanide and of potassium ferrocyanide trihydrate. Ferroelectric transition in the trihydrate

Photolysis of carbon dioxide and methane mixtures at 873 and 293 K with 163.3 nm light

Absolute rate constants for elementary reactions in the chlorination of CH₄, CD₄, CH₃Cl, CH₂Cl₂, CHCl₃, CDCl₃ and CBrCl₃

Kinetics of electrode reactions in liquid ammonia. Part 1.—Hydrogen electrode in acid solution

Thermodynamic studies of fluoroalcohols. Part 3.—The thermodynamics of transfer of five fluoroalcohols from the gas-phase to aqueous solution

Radiolysis of pyrimidines in aqueous solutions. Part 1.—Product formation in the interaction of e–aq, ·H, ·OH and Cl–2· with thymine

Some simple, highly reactive, inorganic chlorine derivatives in aqueous solution. Their formation using pulses of radiation and their role in the mechanism of the Fricke dosimeter

Selective free radical reactions with proteins and enzymes. Reactions of inorganic radical anions with trypsin

Properties of aqueous thorium nitrate solutions. Part 1.—Densities, viscosities, conductivities, pH, solubility and activities at freezing point

Properties of aqueous thorium nitrate solutions. Part 2.—Water activities and osmotic and activity coefficients of thorium nitrate at 25, 35 and 45°C

Knudsen effusion study of silica

Osmotic coefficients of aqueous potassium chloride solutions at 50 and 70°C

Kinetics of ligand-substitution in glycerol at high pressures, by a laser temperature-jump method

Disproportionation–combination reactions of cyclohexyl radicals at low temperature in the solid state

Pulse radiolysis study of the chemiluminescence from luminol. (5-Amino-2,3-dihydrophthalazine-1,4-dione)

Reactivity of clean and oxidized aluminum surfaces towards sulphur compounds

Solvent–solute interactions in moderate and high dielectric constant solvents

Sorption–diffusion in heterogeneous systems. Part 5.—A general diffusion/immobilization model

Sorption–diffusion in heterogeneous systems. Part 6.—General behaviour of diffusion-controlled competitive sorption processes

Studies in ion solvation in non-aqueous solvents and their aqueous mixtures. Part 16.—Free energies of transfer of sodium bromide and iodide from water to 10–99%(w/w) methanol + water mixtures at 25°C

Thermodynamic properties of aliphatic halogen compounds. Part 2.—Heat capacity of 1,1,1-trichloroethane

Reviews of books ( Journal of the Chemical Society, Faraday Transactions 1 Vol -69 )

Oxidation of n-alkanes photosensitized by 1-naphthol

Dissociation of 3-hydroxybut-1-ene and the resonance energy of the hydroxyallyl radical

H-bonding on solid oxide surfaces. Infra-red spectroscopic study of the adsorption of alcohols on silica and alumina

Homogeneous hydrogen absorption and hydrogen exchange reactions by 1:1 and 1:2 electron donor–acceptor complexes of various aromatic hydrocarbons with alkali metals

Activity coefficients and association of n-alkanols in n-octane

Hydrogenation of olefins. Part 7.—Reaction of ethylene with deuterium catalyzed by silica-supported rhenium

Thermodynamics of adsorption of a series of related organic molecules on graphite and on a carbon black. Part 2.—Entropies of adsorption

Photoionization study of clustering reactions in diamines: ethane-1,2-diamine, propane-1,2-diamine and propane-1,3-diamine

Reactions of trifluoromethyl radicals with propane, n-butane and isobutane

Thermal decomposition of Δ¹-3,3,4,4-tetrafluorodiazetidine

Investigation of temperature dependence of the interaction second virial coefficient using gas–liquid chromatography

Thermal decomposition of oxalates. Part 13.—Surface area changes in the thermal decomposition of uranyl oxalate

Thermodynamics of polydimethylsiloxane solutions

Exothermic heats of dilution in non-polar polymer solutions

Reactions of energetic hydrogen atoms with simple hydrocarbons. Part 2.—Substitution reactions in ethane

Polymerization of methyl α-cyanoacrylate. Part 1.—Initiation by benzoyl peroxide

Charge trapping phenomena in anthracene crystals and the influence of crystal deformation

Reviews of books ( Journal of the Chemical Society, Faraday Transactions 1 Vol -69 )

Kinetics of the reaction of hydroxyl radicals with ethylene and with C₃ hydrocarbons

Combined effects of temperature and pressure upon the charge transfer to solvent spectrum of iodide in water and non-aqueous solvents. Local structural effects and ion pair formation

Stability of dispersions in non-aqueous media. Part 8.—Theoretical analysis of heterocoagulation

Growth of crystals from the gas phase. Part 4.—Growth of gallium arsenide by chemical vapour transport, and the influence of compositional convection

Consequences of assuming a maxwellian energy distribution for adsorption sites

Dissociation constant of 2,6-dihydroxybenzoic acid in water and in deuterium oxide at 25°C

Radiolysis of ethylene + ethanol systems. Part 2.—Telomerization reactions at high pressures

Thermal conductivity of liquid toluene at high pressures

Pyrolysis of nitrogen dioxide in the shock tube

Calculation of vapour pressures from effusion measurements for dissociated vapours

Electron paramagnetic resonance study of catalysts derived from molybdenum hexacarbonyl

Pressure against composition isotherms and thermodynamic data for the α-phase of the palladium/hydrogen system

Molecular complexes. Part 8.—Rationalization of the use of the molal scale for processing nuclear magnetic resonance data

Molecular complexes. Part 9.—Studies by a phase distribution procedure which employs nuclear magnetic resonance spectroscopy for quantitative measurements

Molecular complexes. Part 10.—Theory for complex formation and nuclear magnetic resonance evidence for short range molecular order in liquids

Activity coefficients of some alkali-metal halides in ethylene glycol solution from electromotive force measurements

Solubility of H₂ and CO in molten alkali-metal nitrates

Interaction of gases with ionic melts. Solubility of carbon dioxide and ammonia in molten alkali-metal nitrates

High-temperature thermodynamic properties of the alkali-metal fluorides

Primary processes in acetone radiolysis

Determination of excess Gibbs functions of binary liquid mixtures from measurements of dew pressure and composition of vapour. Test of the method on benzene + cyclohexane

Reaction of methylene with cyclobutane. Part 2.—Excess energy carried by singlet methylene

Infra-red study of the reactions between ethyl isocyanate and silica surfaces

Interaction of theophylline and phenobarbital in solution

Gas–liquid chromatography measured activity coefficients in non-electrolyte solutions

Kinetics of the addition of triethylaluminium to alkenes in hydrocarbon solution

Photoenolization of ortho-methyl-substituted acetophenones: solvent effects on the triplet state reactivity

Effect of irradiation on electrode processes. Part 2.—Diffusion currents associated with radiolytic products

Thermodynamic properties of organic compounds in aqueous solutions. Apparent molal heat capacities of amines and ethers

Direct measurement of the rate of reaction of the methyl radical with sulphur dioxide

Surface probing of synthetic faujasites by adsorption of carbon dioxide. Part 2.—Infra-red study of carbon dioxide adsorbed on × zeolites exchanged with mono- and bi-valent ions

Adsorption and decomposition of acetylene on evaporated metal films

Adsorption of benzene and cyclohexane on faujasite-type zeolites. Part 1.—Thermodynamic properties at low coverage

Adsorption of benzene and cyclohexane on faujasite-type zeolites. Part 2.—Adsorption site efficiency and zeolite field influence at high coverage

Transport of single gases and of binary gas mixtures in a microporous carbon membrane

Solid/liquid phase equilibria in the mixtures methane + n-hexane and methane + n-pentane

Transport processes in binary and ternary mixtures containing water, triethylamine and urea. Part 1.—Intradiffusion and viscosity coefficients

Transport processes in binary and ternary mixtures containing water, triethylamine and urea. Part 2.—Mutual diffusion coefficients in the triethylamine + water system at 5 and 15°C

Diene reactions. Part 2.—Retardation by isoprene of polymerization initiated by Ni{P(OPh)₃}₄+ CCl₄—a novel termination reaction

Content Provider	Royal Society of Chemistry (RSC)
Author	Bamford, C. H. Ashworth, J.
Copyright Year	1973
Abstract	We have found that the polymerization of methyl methacrylate initiated by tetrakis(triphenyl phosphite)nickel(0)(Ni(tp)4) and carbon tetrachloride is strongly retarded by dienes. During reaction the solutions develop an absorption spectrum very similar to that of the π-allylic complex of NiII described in the preceding paper. In systems containing isoprene (is) the rate of increase of absorbance becomes independent of [is] and the rate of polymerization becomes insignificant when [is] > 0.1 mol dm–3. At lower [is] the molecular weight of the polymer falls steadily with increasing [is]. The retardation reaction is shown to involve the attack of a propagating polymer radical on an unstable NiI species, generating a terminal π-allylic derivative in the polymer chain. This is the major termination reaction for [is] 0.02 mol dm–3, so that under these conditions nearly all polymer chains carry a terminal π-allylic unit, and the molecular weight may be estimated from the absorbance.An approximate kinetic treatment relating rates of polymerization and development of absorbance and polymer molecular weights is presented.
Starting Page	314
Ending Page	321
Page Count	8
File Format	PDF
ISSN	03009599
Volume Number	69
Journal	Journal of the Chemical Society, Faraday Transactions 1
DOI	10.1039/F19736900314
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Absorption spectroscopy Triphenyl phosphite Tissue paper Carbon tetrachloride Polymerization Polymer Nickel Methyl methacrylate Isoprene
Content Type	Text
Resource Type	Article
Subject	Chemistry

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