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| Content Provider | Royal Society of Chemistry (RSC) |
|---|---|
| Author | Dainton, Frederick McCracken, D. R. Buxton, G. V. |
| Copyright Year | 1973 |
| Abstract | Reaction of the hyper-reduced metal ions Ni+, Co+ and Cd+ with N2O produces N2 and a hyper-oxidised state M(III) of the metal ion by oxygen atom transfer. When formate is present a chain reaction occurs showing that CO–2 reduces M2+, and that M(III) reacts with formate ion to produce CO–2. Detailed studies of the chain reaction kinetics show that M(III) exists in at least two forms, one probably being a hydrolysis product of the other. With nickel (and probably cadmium) M(III) is not stable and is either chemically similar to the hydroxyl radical or produces it on hydrolysis, e.g., [graphic omitted] With cobalt, a long lived (hours) Co(III) state is formed which may be Co(OH)3. |
| Starting Page | 243 |
| Ending Page | 254 |
| Page Count | 12 |
| File Format | |
| ISSN | 03009599 |
| Volume Number | 69 |
| Journal | Journal of the Chemical Society, Faraday Transactions 1 |
| DOI | 10.1039/F19736900243 |
| Language | English |
| Publisher | Royal Society of Chemistry |
| Access Restriction | Open |
| Subject Keyword | Hydrolysis Cadmium Oxygen Chain reaction Ion Nickel Cobalt Hydroxyl radical |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry |
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