NDLI: Adsorption of bifunctional nitriles at the free water surface and the mercury/water interface

Content Provider	Royal Society of Chemistry (RSC)
Author	Mingozzi, Silvio Trasatti, Sergio Daghetti, Anna Zagòrska, Irwina Koczorowski, Zbigniew
Copyright Year	1983
Abstract	The adsorption of aliphatic bifunctional nitriles (succinonitrile and glutaronitrile) at the air/solution and the uncharged Hg/solution interface has been investigated by means of surface tension, interfacial tension and surface potential measurements. Results have shown that the dinitriles behave differently at the two interfaces in terms of both surface pressure and adsorption potential shifts. Both enhanced electronic effects at the metal surface arising from the flat orientation of the adsorbates and the possibility of diverse spatial configurations of the organic molecules are identified as conceivable reasons for the observed behaviour.
Starting Page	2801
Ending Page	2812
Page Count	12
File Format	PDF
ISSN	03009599
Volume Number	79
Issue Number	12
Journal	Journal of the Chemical Society, Faraday Transactions 1
DOI	10.1039/F19837902801
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Adsorption Aliphatic compound Surface tension Succinonitrile
Content Type	Text
Resource Type	Article
Subject	Chemistry

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Adsorption of bifunctional nitriles at the free water surface and the mercury/water interface