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Front cover

Contents pages

Spectroscopy of the Rydberg states of SO in a supersonic jet

Rotational spectra of tert-butyl bromide and iodide measured in the millimetre-wave region and by Fourier-transform techniques

Rate constants for the de-excitation of the bending vibrational levels of NCO(X) by helium, neon, argon, krypton and xenon

Time-resolved studies of the temperature dependence of the gas-phase reactions of methylsilylene with silane and the methylsilanes

Kinetic studies and ab initio investigations of the reactions of atomic bromine with methylsilane and dimethylsilane

Rates of reaction between the nitrate radical and some aliphatic esters

Kinetics and product study of the self-reactions of allyl and allyl peroxy radicals at 296 K

Reaction of methyl radicals with azoethane

Kinetics and mechanism of the thermal gas-phase reaction between trifluoromethylhypofluorite, CF₃OF, and trichloroethene

Spectroscopic properties of a triarylpyrylium cation

Excited-state reactions of triphenylpyrylium ion with cinnamate derivatives: triplet-mediated isomerization and singlet-mediated dimerization

Mean reaction times in non-homogeneous kinetics

Pulse radiolysis study on radical cations of alkyl bromides in aqueous solutions

Temperature dependence of the rate constant for the reaction H + OH in liquid water up to 200 °C

Intramolecular hydrogen bond and molecular conformation. Part 1.—Effect of pressure and temperature on the infrared spectra of 4-hydroxy-4-methylpentan-2-one (diacetone alcohol) in dilute solutions

Steric and inductive effects on the basicity of porphyrins and on the site of protonation of porphyrin dianions: radiolytic reduction of porphyrins and metalloporphyrins to chlorins or phlorins

Role of hydrophilic interactions in sustaining preferential orientations: calorimetric and nuclear magnetic resonance studies of ternary aqueous systems containing a destructuring agent and hydroxylated compounds at 298.15 K

Novel differential scanning calorimetric studies of supercooled organic liquids

Moments analysis of strongly coupled diffusion in taylor dispersion profiles. Sodium hydroxide–sodium dodecyl sulfate–water

Electrokinetics of polystyrene latices: the role of the hydrophobic surface

Electrokinetic potential of the alkane/aqueous electrolyte interface

Iron–diimine–cyanide complexes as probes for aqueous micellar systems

Strongly polarized water at the interfacial region in reversed micelles containing 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecanenickel(II) as a probe

block-Copoly(oxyethylene/oxybutylene/oxyethylene), E₄₀B₁₅E₄₀, in aqueous solution: micellisation, gelation and drug release

Study of the anodic oxidation of stainless steel alloys, and their constituent elements, in acidic electrolytes

Percolation model of adsorption-induced response of the electrical characteristics of polycrystalline semiconductor adsorbents

Dynamic simulation of the adsorption of a flexible chain

Infrared and quantitative adsorption study of coordinatively unsaturated cations on magnesium hydroxide

Reactions of hydrocarbons over Ru/SiO₂: exchange with deuterium and the onset of hydrogenolysis

Reversible redox behaviour between silver cations and silver metal particles in hydrated Ag-Y zeolites

Corrigendum

Back cover

Back matter

Rates of reaction between the nitrate radical and some aliphatic esters

Content Provider	Royal Society of Chemistry (RSC)
Author	Langer, Sarka Wängberg, Ingvar Ljungström, Evert
Copyright Year	1993
Abstract	Rate coefficients for the reaction of NO3 with methyl formate, methyl acetate, methyl propionate, methyl butylrate, ethyl formate, ethyl acetate, ethyl propionate, propyl formate, propyl acetate and n-hexane have been determined at 296 ± 2 K. The rate coefficients, which should strictly be interpreted as upper limits, were found to be 0.36 ± 0.08, 0.7 ± 0.2, 3.3 ± 0.8, 4.8 ± 0.5, 1.7 ± 0.3, 1.3 ± 0.3, 3.3 ± 0.4, 5.4 ± 0.9, 5 ± 2 and 14.7 ± 3.0, respectively (in units of 10–17 cm3 molecule–1 s–1). The activation energy for the reaction between ethyl acetate and NO3 was determined to be 23 ± 8 kJ mol–1 between 273 and 373 K. The rate coefficients for aliphatic esters may be predicted from available group reactivity factors for alkanes provided that formate carbonyl hydrogen atoms are treated as primary hydrogen atoms.
Starting Page	425
Ending Page	431
Page Count	7
File Format	PDF
ISSN	09565000
Volume Number	89
Issue Number	3
Journal	Journal of the Chemical Society, Faraday Transactions
DOI	10.1039/FT9938900425
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Methyl formate Aliphatic compound Hydrogen Propionic acid Ethyl formate Reaction rate constant Ethyl acetate Formic acid Hexane Methyl acetate Carbonyl group Activation energy Propyl acetate
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry

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N-Hexane : Ethyl Acetate ( 50 : 50 ) Ethyl Acetate : Methanol ( 80 : 20 ) Ethyl Acetate : Formic Acid : Glacial Acetic Acid : Distilled Water

High-Temperature Measurements of the Reactions of OH with Small Methyl Esters: Methyl Formate, Methyl Acetate, Methyl Propanoate, and Methyl Butanoate

UV absorption cross sections for a series of formates

Anaerobic catabolism of formate to acetate and CO2 by Butyribacterium methylotrophicum.

The Determination of the Constants in the System of Methyl Alcohol, Formic Acid, Methyl Formate and Water

Structure of proton disolvates formed in the acid hydrolysis of ethyl formate and methyl acetate

Microwave spectrum, structure and dipole moment of methyl nitrate

Amine dehydrogenases: efficient biocatalysts for the reductive amination of carbonyl compounds

Separation of acetic acid/4-methyl-2-pentanone, formic acid/4-methyl-2-pentanone and vinyl acetate/ethyl acetate by extractive distillation

Rates of reaction between the nitrate radical and some aliphatic esters

Similar Documents

N-Hexane : Ethyl Acetate ( 50 : 50 ) Ethyl Acetate : Methanol ( 80 : 20 ) Ethyl Acetate : Formic Acid : Glacial Acetic Acid : Distilled Water

High-Temperature Measurements of the Reactions of OH with Small Methyl Esters: Methyl Formate, Methyl Acetate, Methyl Propanoate, and Methyl Butanoate

UV absorption cross sections for a series of formates

Anaerobic catabolism of formate to acetate and CO2 by Butyribacterium methylotrophicum.

The Determination of the Constants in the System of Methyl Alcohol, Formic Acid, Methyl Formate and Water

Structure of proton disolvates formed in the acid hydrolysis of ethyl formate and methyl acetate

Microwave spectrum, structure and dipole moment of methyl nitrate

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Separation of acetic acid/4-methyl-2-pentanone, formic acid/4-methyl-2-pentanone and vinyl acetate/ethyl acetate by extractive distillation

Rates of reaction between the nitrate radical and some aliphatic esters