NDLI: Spin-crossover metal–organic frameworks: promising materials for designing gas sensors

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Inside back cover

Back cover

Journal of Materials Chemistry C Vol - 3 Issue - 5

Journal of Materials Chemistry C Vol -2

Journal of Materials Chemistry C Vol -1

Spin-crossover metal–organic frameworks: promising materials for designing gas sensors

Content Provider	Royal Society of Chemistry (RSC)
Author	Bartual-Murgui, Carlos Thibault, Christophe Molnár, Gábor Salmon, Lionel Akou, Amal Bousseksou, Azzedine Vieu, Christophe
Copyright Year	2015
Abstract	We present a quantitative study of the sensing behavior of micro-patterned gratings based on the metal–organic framework type spin crossover complex Fe(bpac)[Pt(CN)4] (1) in the presence of vapors of various organic compounds. The gratings of 1 were fabricated by combining a sequential assembly technique and a photolithographic method. The guest absorption driven change of the spin state and the associated variation of the refractive index were in situ monitored by optical diffraction on a grating of 1. Our sensor is characterized by good reversibility, room temperature operation, a low limit of detection (∼30 ppm for molecules of iodobenzene) as well as a linear dynamic range of detection (from 300 to 1500 ppm). The possibility of selectively desorbing the analytes by thermal annealing confers also selectivity to the sensor.
Starting Page	1277
Ending Page	1285
Page Count	9
File Format	HTM / HTML PDF
ISSN	20507526
Volume Number	3
Issue Number	6
Journal	Journal of Materials Chemistry C
DOI	10.1039/c4tc02441a
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Spin crossover Photolithography Diffraction Iodobenzene Dynamic range Nucleic acid thermodynamics
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry

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