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| Content Provider | Royal Society of Chemistry (RSC) |
|---|---|
| Author | Dhara, Sandip Das, Arindam Tyagi, Ashok Kumar Sardar, Manas Bonu, Venkataramana |
| Copyright Year | 2015 |
| Abstract | A high value of magnetic moment of 0.08 emu g−1 at room temperature for SnO2 nanoparticles (NPs) was observed. Surface functionalization with octadecyltrichlorosilane (OTS) enhanced the saturation magnetic moment of NPs to an anomalously high value of 0.187 emu g−1 by altering the electronic configuration on the NPs surface. Surface functionalization also suppressed photoluminescence (PL) peaks arising from oxygen defects around 2 eV and caused an increase in the intensities of two peaks near the violet region (2.6–3 eV). PL studies under a uniform external magnetic field enriched the understanding of the role of OTS. Both OTS and external magnetic fields significantly modulated the luminescence spectra by altering the surface electronic structure of NPs. Extra spins on the surface of SnO2 NPs created by the surface functionalization process and their influence on resultant magnetic moment and luminescence properties are discussed in detail. |
| Starting Page | 1261 |
| Ending Page | 1267 |
| Page Count | 7 |
| File Format | HTM / HTML PDF |
| ISSN | 20507526 |
| Volume Number | 3 |
| Issue Number | 6 |
| Journal | Journal of Materials Chemistry C |
| DOI | 10.1039/c4tc02210f |
| Language | English |
| Publisher | Royal Society of Chemistry |
| Access Restriction | Open |
| Subject Keyword | OTS Magnetic moment Photoluminescence Oxygen Electronvolt Viola odorata Magnetic field Luminescence |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Materials Chemistry |
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