NDLI: Mechanism of chemical doping in electronic-type-separated single wall carbon nanotubes towards high electrical conductivity

Please wait, while we are loading the content...

Boronate ester post-functionalization of PPEs: versatile building blocks for poly(2,2′-(1-(4-(1,2-di(thiophen-2-yl)vinyl)phenyl)-2-(2,5-dioctylphenyl)ethene-1,2-diyl)dithiophene) and application in field effect transistors

Oxygen diffusion dynamics in organic semiconductor films

Theoretical investigation of armchair silicene nanoribbons with application in stretchable electronics

Swelling of PDMS networks in solvent vapours; applications for passive RFID wireless sensors

A 2D quantum dot-based electrochemiluminescence film sensor towards reversible temperature-sensitive response and nitrite detection

Synthesis, luminescence properties, and growth mechanisms of YF₃:Yb³⁺/Er³⁺ nanoplates

Heating-up synthesis of cadimum-free and color-tunable quaternary and five-component Cu–In–Zn–S-based semiconductor nanocrystals

Gold nanoparticle density-multiplication by tuning block copolymer self-assembly processes toward increased charge storage

Effect of the functionalized π-bridge on porphyrin sensitizers for dye-sensitized solar cells: an in-depth analysis of electronic structure, spectrum, excitation, and intramolecular electron transfer

Simultaneous luminescence modulation and magnetic field detection via magneto-optical response of Eu³⁺-doped NaGdF₄ nanocrystals

Ferromagnetic hierarchical carbon nanofiber bundles derived from natural collagen fibers: truly lightweight and high-performance microwave absorption materials

Facile interfacial synthesis of large sized 3D gold spherical architectures with strong individual particle SERS response and high reproducibility

Strong optical nonlinearity of the nonstoichiometric silicon carbide

Green-blue light-emitting platinum(ii) complexes of cyclometallated 4,6-difluoro-1,3-dipyridylbenzenes showing mesophase organisation

The effect of Co doping on the conductive properties of ferromagnetic Zn_xCo_1−xO films

Enhanced photovoltaic performance and morphological control of the PbS counter electrode grown on functionalized self-assembled nanocrystals for quantum-dot sensitized solar cells via cost-effective chemical bath deposition

Ce dopant effects on NaYF₄ particle morphology and optical properties

Peripheral versus axial substituted phthalocyanine-double-walled carbon nanotube hybrids as light harvesting systems

Heteroatom induced contrasting effects on the stimuli responsive properties of anthracene based donor–π–acceptor fluorophores

Achieving hierarchical hollow carbon@Fe@Fe₃O₄ nanospheres with superior microwave absorption properties and lightweight features

Strong CIE activity, multi-stimuli-responsive fluorescence and data storage application of new diphenyl maleimide derivatives

The synthesis and flash memory behavior of alternate copolymer containing carbazole donor and perylenediimide derivatives acceptor by the hybridization of organo-silicon

Mechanism of chemical doping in electronic-type-separated single wall carbon nanotubes towards high electrical conductivity

Lutetium doping for making big core and core–shell upconversion nanoparticles

Sensing single molecules with carbon–boron-nitride nanotubes

Construction of multi-layered white emitting organic nanoparticles by clicking polymers

Tailored sunlight driven nano-photocatalyst: bismuth iron tungstate (BiFeWO₆)

The impact of atomic layer deposited SiO₂ passivation for high-k Ta_1−xZr_xO on the InP substrate

Salicylaldimine difluoroboron complexes containing tert-butyl groups: nontraditional π-gelator and piezofluorochromic compounds

Unusual structural-disorder stability of mechanochemically derived-Pb(Sc_0.5Nb_0.5)O₃

Correction: Flexible BaTiO₃/PVDF gradated multilayer nanocomposite film with enhanced dielectric strength and high energy density

Back cover

Journal of Materials Chemistry C Vol - 3 Issue - 29

Journal of Materials Chemistry C Vol - 3 Issue - 19

Journal of Materials Chemistry C Vol - 3 Issue - 9

Journal of Materials Chemistry C Vol - 3 Issue - 8

Journal of Materials Chemistry C Vol - 3 Issue - 7

Journal of Materials Chemistry C Vol - 3 Issue - 6

Journal of Materials Chemistry C Vol - 3 Issue - 5

Journal of Materials Chemistry C Vol -2

Journal of Materials Chemistry C Vol -1

Mechanism of chemical doping in electronic-type-separated single wall carbon nanotubes towards high electrical conductivity

Content Provider	Royal Society of Chemistry (RSC)
Author	Bucossi, Andrew R. Puchades, Ivan Landi, Brian J. Cox, Nathanael D. Lawlor, Colleen C. Rossi, Jamie E. Schauerman, Christopher M.
Copyright Year	2015
Abstract	Enhanced electrical conductivity of carbon nanotubes (CNTs) can enable their implementation in a variety of wire and cable applications traditionally employed by metals. Electronic-type-separated single wall carbon nanotubes (SWCNTs) offer a homogeneous platform to quantify the unique physiochemical interactions from different chemical dopants and their stability. In this work, a comprehensive study of chemical doping with purified commercial CNT sheets shows that I2, IBr, HSO3Cl (CSA) and KAuBr4 are the most effective at increasing the electrical conductivity of CNT films by factors between 3× and 8×. These dopants are used with electronic-type-separated SWCNT thin-films to further investigate changes in SWCNT optical absorption, Raman spectra, and electrical conductivity. The dopant effects with semiconducting SWCNTs result in quenching of the S11 and S22 transitions, and a red shift of 8–10 cm−1 of the Raman G′ peak, when compared to a purified SWCNT thin-film. The average electrical conductivity of purified semiconducting SWCNT thin-films is 7.3 × 104 S m−1. Doping increases this conductivity to 1.9 × 105 S m−1 for CSA (2.6× increase), 2.2 × 105 S m−1 for IBr (3.1×), to 2.4 × 105 for I2 (3.3×), and to 4.3 × 105 for KAuBr4 (5.9×). In comparison, metallic SWCNT thin-films exhibit only slight quenching of the optical absorbance spectra for the M11 transition, and shifts in the Raman G′-peak of less than 1 cm−1 for I2 and IBr, whereas KAuBr4 and CSA promote red shifting by 4 cm−1, and 7 cm−1, respectively, when compared to a purified control sample. The increase in electrical conductivity of metallic SWCNT thin-films is gradual and depends on the dopant. With an average value of 9.0 × 104 S m−1 for the purified metallic SWCNT thin-films, I2 doping increases the electrical conductivity to 1.0 × 105 (1.1× increase), IBr to 1.5 × 105 S m−1 (1.7×), KAuBr4 to 2.4 × 105 S m−1 (2.6×), and CSA to 3.2 × 105 S m−1 (3.5×). The time-dependent stability of the chemical dopants with SWCNTs is highest for KAuBr4, which remains in effect after 70 days in ambient conditions. The doping-enhanced electrical conductivity is attributed to the relative potential difference between the SWCNT electronic transitions and the redox potential of the chemical species to promote charge transfer. The results of this work reinforce the chemical doping mechanism for electronic-type-separated SWCNTs and provide a path forward to advance SWCNT conductors.
Starting Page	10256
Ending Page	10266
Page Count	11
File Format	HTM / HTML PDF
ISSN	20507526
Volume Number	3
Issue Number	39
Journal	Journal of Materials Chemistry C
DOI	10.1039/c5tc02053k
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	CNT CSA Raman Electrical resistivity and conductivity Carbon nanotube Dopant SIG Sauer P226 Redox
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Mechanism of chemical doping in electronic-type-separated single wall carbon nanotubes towards high electrical conductivity

Tuning electrical conductivity of CNT-PDMS nanocomposites for flexible electronic applications

Doping on selectivity of naphthalene towards single-wall carbon nanotubes, ” comput. Mater. Sci. 40, 354–358 (2007).

Single-wall carbon nanotubes.

Characterisation of SU-8 n-doping carbon nanotube-based electronic devices

Poly(vinylidene fluoride)-functionalized single-walled carbon nanotubes for the preparation of composites with improved conductivity

A raman study of potassium-doped double- wall carbon nanotubes.

Thermal Conductivity of Single-Wall Carbon Nanotubes

Single wall carbon nanotubes for conductive wiring

Mechanism of chemical doping in electronic-type-separated single wall carbon nanotubes towards high electrical conductivity

Similar Documents

Mechanism of chemical doping in electronic-type-separated single wall carbon nanotubes towards high electrical conductivity

Tuning electrical conductivity of CNT-PDMS nanocomposites for flexible electronic applications

Doping on selectivity of naphthalene towards single-wall carbon nanotubes, ” comput. Mater. Sci. 40, 354–358 (2007).

Single-wall carbon nanotubes.

Characterisation of SU-8 n-doping carbon nanotube-based electronic devices

Poly(vinylidene fluoride)-functionalized single-walled carbon nanotubes for the preparation of composites with improved conductivity

A raman study of potassium-doped double- wall carbon nanotubes.

Thermal Conductivity of Single-Wall Carbon Nanotubes

Single wall carbon nanotubes for conductive wiring

Mechanism of chemical doping in electronic-type-separated single wall carbon nanotubes towards high electrical conductivity