NDLI: Synthesis, characterization, morphological behaviour, and photo- and electroluminescence of highly blue-emitting fluorene-carbazole copolymers with alkyl side-chains of different lengths

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Journal of Materials Chemistry C Vol - 1 Issue - 9

Journal of Materials Chemistry C Vol - 1 Issue - 8

Journal of Materials Chemistry C Vol - 1 Issue - 7

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Synthesis, characterization, morphological behaviour, and photo- and electroluminescence of highly blue-emitting fluorene-carbazole copolymers with alkyl side-chains of different lengths

Content Provider	Royal Society of Chemistry (RSC)
Author	Zucchi, Gaël Pansu, Robert B. Geffroy, Bernard Tondelier, Denis Chaigneau, Marc Ephritikhine, Michel Sergent, Alessandra
Copyright Year	2013
Abstract	Four novel phenyl-end-capped π-conjugated polymers comprising alkyl chains of different lengths were synthesized: the poly(9,9-dihexyl-2,7-fluorene-alt-9,9-dioctylfluorene) (P0), the alternating fluorene–carbazole copolymers P1 and P2 comprising 20% and 50% of carbazole, respectively, and the homopolymer poly(9-hexyl-9H-carbazole) (P3). The non-end-capped alternating fluorene–carbazole copolymer P4 comprising 20% of carbazole was also synthesized for the sake of comparison with P1. P0–P2 and P4 were synthesized by a Pd-catalyzed Suzuki–Miyaura coupling in good yields (80–89%), while P3 was obtained by a Ni-catalyzed Yamamoto coupling reaction from the 3,6-dibromocarbazole monomer in a moderate yield (52%). P0–P4 polymers were characterized by NMR, elemental analysis, and GPC. The molecular weights are 40.30, 23.42, 14.33, 3.92, and 37.49 kDa, with polydispersity indices of 2.5, 1.7, 1.8, 1.3, and 2.6, for P0, P1, P2, P3, and P4, respectively. These polymers were found to show a high thermal stability, with decomposition temperatures in the range of 395–420 °C, and the glass transition temperature was found to regularly increase with the amount of carbazole inserted in the conjugated backbone. AFM images obtained on thin films (thickness of about 90 nm) of P0–P2 revealed films with surfaces of good quality, being homogeneous with low roughness (0.2 nm for the smaller ones). These polymers were found to be blue-emitting both in diluted dichloromethane and chlorobenzene solutions as well as in thin films and exhibit relatively high values of the absolute quantum yields in the range of 100–5.5% in dichloromethane and 51.4–7.7% in thin films. Blue-emitting electroluminescent devices were obtained with P0 and P1 as emitting layers, respectively. The device built with P1 showed improved performances (EQE of 1.32%) with respect to the one built with the parent polyfluorene material (EQE of 0.75%).
Starting Page	3207
Ending Page	3216
Page Count	10
File Format	HTM / HTML PDF
ISSN	20507526
Volume Number	1
Issue Number	19
Journal	Journal of Materials Chemistry C
DOI	10.1039/c3tc00060e
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	EQE Suzuki Yamamoto Alkyl Carbazole Polymer Copolymer Coupling reaction Monomer Nuclear magnetic resonance Dispersity Glass transition Dichloromethane Chlorobenzene Quantum tunnelling Electroluminescence
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry

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