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| Content Provider | Royal Society of Chemistry (RSC) |
|---|---|
| Author | Huang, Lihui Hua, Youjie Wang, Huanping Xu, Shiqing Deng, Degang Jia, Guohua Li, Chenxia Yu, Hua Li, Yinqun Zhao, Shilong Li, Yinyan |
| Copyright Year | 2013 |
| Abstract | A red-emitting phosphor, Eu2+-activated Ca4(PO4)2O phosphor was synthesized by conventional solid-state reaction. X-ray powder diffraction confirmed the phase formation. The band gap of Ca4(PO4)2O was estimated to be about 4.75 eV from the diffuse reflection spectrum. The excitation and emission spectra, and the concentration dependence of emission intensity were investigated. The results showed that under excitation at 460 nm, the Ca4(PO4)2O:Eu2+ phosphors exhibit strong red emission centered at 665 nm, and the optimum concentration of Eu2+ in Ca4(PO4)2O:Eu2+ is about 0.07 mol per mol Ca2+ ions. The nature of the Eu2+ ion emission in Ca4(PO4)2O, i.e. the main mechanism for concentration quenching was discussed. A white LED was fabricated using a blue 460 nm chip pumped by a phosphor blend of green-emitting Sr2SiO4:Eu2+ and red-emitting Ca3.93(PO4)2O:0.07Eu2+. When the applied current was 20 mA, the white LED has Commission International de I'Eclairage color coordinates of (0.3135, 0.3316) for white light (correlated color temperature = 6446 K) and an excellent color rendering index of 90.5. |
| Starting Page | 3194 |
| Ending Page | 3199 |
| Page Count | 6 |
| File Format | HTM / HTML PDF |
| ISSN | 20507526 |
| Volume Number | 1 |
| Issue Number | 19 |
| Journal | Journal of Materials Chemistry C |
| DOI | 10.1039/c3tc30148f |
| Language | English |
| Publisher | Royal Society of Chemistry |
| Access Restriction | Open |
| Subject Keyword | Powder diffraction Band gap Electronvolt Diffuse reflection Correlation and dependence Emission intensity Ion Color temperature |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Materials Chemistry |
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