NDLI: Precisely controllable fabrication of Er<sup>3+</sup>-doped glass ceramic fibers: novel mid-infrared fiber laser materials

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Precisely controllable fabrication of Er³⁺-doped glass ceramic fibers: novel mid-infrared fiber laser materials

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Journal of Materials Chemistry C Vol - 5 Issue - 9

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Precisely controllable fabrication of Er³⁺-doped glass ceramic fibers: novel mid-infrared fiber laser materials

Content Provider	Royal Society of Chemistry (RSC)
Author	Huang, Xiongjian Chen, Zhi Qiu, Jianrong Xiao, Xiudi Kang, Shiliang Yang, Dandan Dong, Guoping Fang, Zaijin
Copyright Year	2017
Abstract	We demonstrated remarkably enhanced 2.7 μm emission in glass-ceramic (GC) fibers containing NaYF4:Er3+ nanocrystals with 980 nm excitation for the first time. The melt-in-tube technique is of scientific and technical significance for the fabrication of GC fibers in comparison to the conventional rod-in-tube technique. The obtained precursor fibers, in which the structure can be maintained well, exhibit no obvious element diffusion or crystallization during the fiber-drawing process. After a careful heat treatment, NaYF4 nanocrystals were controllably precipitated in the glass fiber core. Owing to the incorporation of Er3+ ions into the low phonon energy NaYF4 nanocrystals, enhanced 2.7 μm emission was achieved from the Er3+-doped GC fibers, which was almost undetectable in precursor fibers due to the high phonon energy of the borosilicate glass fiber matrix. Moreover, the 2.7 μm emission lifetime was obtained due to the excellent emission properties of Er3+ in the GC fibers. The transmission loss values of precursor fibers and GC fibers at 1310 nm were measured to be 7.44 dB m−1 and 11.81 dB m−1, respectively. In addition, a theoretical simulation based on the rate equations and propagation equations was performed to evaluate the possibility of 2.7 μm laser output. The excellent optical properties endow the GC fibers with potential applications for mid-infrared fiber lasers.
Starting Page	4549
Ending Page	4556
Page Count	8
File Format	HTM / HTML PDF
ISSN	20507526
Volume Number	5
Issue Number	18
Journal	Journal of Materials Chemistry C
DOI	10.1039/c7tc00988g
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Micrometre Glass-ceramic Diffusion Glass fiber Phonon Treatment as prevention Borosilicate glass Composite material Laser
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry

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